Confinement effects on the stimulated dissociation of molecular Bose-Einstein condensates.

Phys Rev Lett

Department of Chemistry, Ben-Gurion University of the Negev, P.O.B. 653, Beer-Sheva 84105, Israel.

Published: February 2007

We show that a molecular Bose-Einstein condensate in a trap is stabilized against stimulated dissociation if the trap size is smaller than the resonance healing length (Planck's 2/2mgsqrt[n]);1/2. The condensate shape determines the critical atom-molecule coupling frequency. We discuss an experiment for triggering dissociation by a sudden change of coupling or trap parameters. This effect demonstrates one of the unique collective features of "superchemistry" in that the yield of a chemical reaction depends critically on the size and shape of the reaction vessel.

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http://dx.doi.org/10.1103/PhysRevLett.98.080403DOI Listing

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