We have performed thermodynamic and neutron scattering measurements on the S=1/2 kagomé lattice antiferromagnet ZnCu3(OH)6Cl2. The susceptibility indicates a Curie-Weiss temperature of theta CW approximately = -300 K; however, no magnetic order is observed down to 50 mK. Inelastic neutron scattering reveals a spectrum of low energy spin excitations with no observable gap down to 0.1 meV. The specific heat at low-T follows a power law temperature dependence. These results suggest that an unusual spin liquid state with essentially gapless excitations is realized in this kagomé lattice system.
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http://dx.doi.org/10.1103/PhysRevLett.98.107204 | DOI Listing |
Materials (Basel)
January 2025
MOE Key Laboratory of New Processing Technology for Nonferrous Metals and Materials, School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China.
The RE-M-Ge systems (RE: rare earths, M: transition group elements) contain a large number of compounds with special magnetic properties. A novel compound ErMnGe was found during the investigation on the phase diagram of the Er-Mn-Ge ternary system, and its crystal structure and magnetic properties were investigated. Powder X-ray diffraction results show that ErMnGe crystallizes in an orthorhombic YNiSi-type structure with the space group Pnma (No.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Institute of Materials Engineering, University of Silesia in Katowice, 75 Pułku Piechoty 1A, 41-500 Chorzów, Poland.
Manganese-based alloys with the composition MnFeZ (Z = Si, Al) have been extensively investigated in recent years due to their potential applications in spintronics. The MnFeSi alloy, prepared in the form of ingots, powders, or ribbons, exhibits either a cubic full-Heusler (2) structure, an inverse-Heusler (XA) structure, or a combination of both. In contrast, the MnFeAl alloy has so far been synthesized only in the form of ingots, featuring a primitive cubic (β-Mn type) structure.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China.
The exploration of materials with nanoscale noncollinear configurations has been continuously attracting attention due to the prospective applications in high-performance magnetic devices. Compared to ferromagnetic materials, noncollinear structures in frustrated magnets hold greater research value due to their smaller sizes and unique properties. However, an effective description of the nanoscale noncollinear domain structures in frustrated magnets is lacking.
View Article and Find Full Text PDFInorg Chem
January 2025
Department of Chemistry and Biochemistry, The Ohio State University, Columbus, Ohio 43210, United States.
Three new hexagonal perovskites with CsMMRhCl (M = Na, Ag; M = Mn, Fe) stoichiometry have been synthesized from solution precipitation reactions. These air-stable compounds crystallize as triply cation-ordered variants of the 6H perovskite structure. This structure contains octahedra that share a common face to form MRhCl dimers that are arranged on a two-dimensional triangular network.
View Article and Find Full Text PDFActa Crystallogr B Struct Sci Cryst Eng Mater
February 2025
Neutron Scattering Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.
The search for a Kitaev quantum spin liquid in crystalline magnetic materials has fueled intense interest in the two-dimensional honeycomb systems. Many promising candidate Kitaev systems are characterized by a long-range-ordered magnetic structure with an antiferromagnetic zigzag-type order, where the static moments form alternating ferromagnetic chains. Recent experiments on high-quality single crystals uncovered the existence of intriguing multi-k magnetic structures, which evolved from zigzag structures.
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