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Metamagnetic Behavior in a Quadruple Perovskite Oxide.
Inorg Chem
May 2021
Department of Materials Science, Graduate School of Engineering, Osaka Prefecture University, 1-2 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8570, Japan.
A cubic quadruple perovskite oxide CeMnCrO has been synthesized under high-pressure and high-temperature conditions of 8 GPa and 1273 K. The X-ray absorption spectroscopy reveals that the Ce ions are in a trivalent state, as represented by the ionic model of CeMnCrO. The magnetic study demonstrates three independent antiferromagnetic transitions attributed to Ce (∼10 K), Mn (46 K), and Cr (133 K) ions.
View Article and Find Full Text PDFNi[LnCl] (Ln = Eu, Ce, Gd): the first Ln compounds stabilized in a pure inorganic lattice.
Chem Commun (Camb)
July 2018
Universidad Andres Bello, Facultad de Ciencias Exactas, Departamento de Ciencias Químicas, Santiago, Chile.
Here we report the first examples of 3d-4f compounds based on LnII cations. We have obtained a series of Ni2[LnCl6] isostructural compounds where LnII = Ce 1, Eu 2 and Gd 3 which were characterized in a cubic crystalline system with a Fm3[combining macron]m space group. Magnetic and optical characterization was also performed on this new class of compounds.
View Article and Find Full Text PDFA cubic 3d-4f structure with only ferromagnetic Gd-Mn interactions.
Angew Chem Int Ed Engl
June 2007
School of Chemistry, University of Hyderabad, Hyderabad - 500046, India.
Two 3D supramolecular polymers constructed from an amino acid and a high-nuclear Ln6Cu24 cluster node.
Chemistry
August 2004
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.
The first successful attempt to construct 3D supramolecular frameworks with high-nuclear 3d-4f heterometallic clusters as a node is reported. The self-assembly of Ln3+, Cu2+ and amino acid in solution leads to the formation of two polymers, 35-nuclear complex [Sm6Cu29] 1 with a primitive cubic net-like structure and 36-nuclear complex [Nd6Cu30] 2 with a face-centred cubic network type structure. Glycine and L-proline, respectively, were used as ligands.
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