The purpose of this paper is to study the acoustic behavior of highly heterogeneous, low density porous structures having a complex pore size distribution using two distinct theoretical approaches. The first approach requires the direct numerical integration of the Biot viscosity correction function. The main requirement here is a knowledge of the probability density function of the pore size, which can be achieved by an optical pore-counting technique. The fact that the observed pore size distribution in these materials could be distinctively split into two parts suggested the use of the second approach based upon the double-porosity theory by Olny and Boutin [J. Acoust. Soc. Am. 114(1), 73-89 (2003)]. The latter approach assumes a low permeability contrast between the two porous scales so that the acoustic properties could be estimated using the semi-phenomenological models of Johnson and Lafarge for the viscous and thermal dynamic permeabilities. Numerical results predicted by the two models are then compared with impedance tube experimental data showing good accuracy of the selected prediction methods.
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http://dx.doi.org/10.1121/1.2427114 | DOI Listing |
Langmuir
January 2025
Hubei Key Laboratory of Oil and Gas Exploration and Development Theory and Technology (China University of Geosciences), Wuhan 430074, China.
The strong solid-liquid interaction leads to the complicated occurrence characteristics of shale oil. However, the solid-liquid interface interaction and its controls of the occurrence state of shale oil are poorly understood on the molecular scale. In this work, the adsorption behavior and occurrence state of shale oil in pores of organic/inorganic matter under reservoir conditions were investigated by using grand canonical Monte Carlo (GCMC) and molecular dynamics (MD) simulations.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Chinese Academy of Sciences Fujian Institute of Research on the Structure of Matter, Key Laboratory of Structural Chemistry, CHINA.
One-step adsorptive purification of ethylene (C2H4) from ternary mixture comprising of acetylene (C2H2), ethylene (C2H4) and carbon dioxide (CO2) is a great challenge in the chemical industry. Herein, a microporous metal-organic framework (FJI-H38) has been reported, which possesses a high density of electronegative O/N binding sites and appropriate pore size. Notably, at 0.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, P. R. China.
Alkaline phosphatase (ALP) is a biomarker for many diseases, and monitoring its activity level is important for disease diagnosis and treatment. In this study, we used the microdroplet technology combined with an laser-induced polymerization method to prepare the Ag nanoparticle (AgNP) doped hydrogel microbeads (HMBs) with adjustable pore sizes that allow small molecules to enter while blocking large molecules. The AgNPs embedded in the hydrogel microspheres can provide SERS activity, improving the SERS signal of small molecules that diffuse to the AgNPs.
View Article and Find Full Text PDFMar Pollut Bull
January 2025
Suganthi Devadason Marine Research Institute, Tuticorin, Tamil Nadu, India; Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli, Tamil Nadu, India.
This research investigated the relationship between microplastic accumulation and the sediment texture in seagrass meadows across the selected coastal regions of Tuticorin. Sixteen sediment samples were collected by SCUBA divers utilizing a stainless steel grab sampler. Findings indicate significantly elevated microplastic concentrations in seagrass sediments when compared to unvegetated areas.
View Article and Find Full Text PDFJ Chromatogr A
January 2025
State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), Collaborative Innovation Center for Guangxi Ethnic Medicine, School of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Guilin 541004, PR China. Electronic address:
Herein, using 1,3,5-triformylphloroglucinol (Tp) and 4,4',4″-(1,3,5-triazine-2,4,6-triyl) tris(1,1'-biphenyl) trianiline (Ttba) as ligands, nitrogen-rich triazine unit-based covalent organic frameworks (COFs) with a suitable pore size, named TpTtba-COFs, were synthesized, and they were employed as adsorbents for the extraction and detection of three bisphenols (BPs)-BP A (BPA), BP B (BPB), and BP S (BPS)-in water. Using 2,4,6-tris(4-aminophenyl)-1,3,5-triazine (Tapt) and 1,3,5-tris(4-aminophenyl)benzene (Tapb) ligands as substitutes for Ttba, nitrogen-rich triazine unit-based COFs with a smaller pore size and nitrogen-poor triazine unit-based COFs, named TpTapt-COFs and TpTapb-COFs, respectively, were also prepared for comparison. The adsorption performances of the three COF adsorbents with regard to the three BPs were tested.
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