A new chiral diiron catalyst for enantioselective epoxidation.

Chem Commun (Camb)

Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, Université Joseph Fourier, CNRS, UMR 5047, CEA DSV/DRDC/CB, Grenoble, France.

Published: March 2007

The dinuclear chiral complex Fe(2)O(bisPB)(4)(X)(2)(ClO(4))(4) (X = H(2)O or CH(3)CN) catalyzes with high efficiency (up to 850 TON) and moderate enantioselectivity (63%) the epoxidation of electron deficient alkenes at 0 degrees C by a peracid.

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Source
http://dx.doi.org/10.1039/b616172cDOI Listing

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