PFG NMR methods are frequently used as a means of probing both coherent and incoherent molecular motions of fluids contained within heterogeneous porous media. The time scale over which molecular displacements can be probed in a conventional PFG NMR experiment is limited by the relaxation characteristics of (1)H - the nucleus that is typically observed. In multiphase systems, due to its sensitivity to susceptibility gradients and interactions with surfaces,(1)H signal is frequently characterized by rapid T(1) and T(2) relaxation. In this work, a heteronuclear approach to PFG NMR is demonstrated which allows the study of molecular displacement over extended time scales (and, consequently, length scales) by exploiting the longer relaxation time of (13)C. The method presented employs the DEPT technique of polarization transfer in order to enhance both the sensitivity and efficiency of (13)C detection. This hybrid coherence transfer PFG technique has been used to acquire displacement propagators for flow through a bead pack with an observation time of up to 35 s.
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http://dx.doi.org/10.1016/j.jmr.2007.02.001 | DOI Listing |
Chemphyschem
November 2024
Institute of Chemistry, University of Potsdam, Karl-Liebknecht-Straße 24-25, 14476, Potsdam-Golm, Germany.
A range of protic ionic liquids (PILs) based on tri-n-alkylammonium cations and mesylate/triflate anions were incorporated into a polymer matrix to form ionogels (IGs). These systems were investigated for their thermal and electrochemical behaviour, as well as under the aspect of ion motion via PFG-NMR. The ionic conductivities of the ILs/IGs are in the range of 10-10 S/cm at elevated temperatures and the diffusion coefficients are around 10 m s.
View Article and Find Full Text PDFChemSusChem
November 2024
I3N, Cenimat, Department of Materials Science (DCM), NOVA School of Science and Technology, NOVA University of Lisbon, Caparica, 2829-516, Portugal.
Gel polymer electrolytes (GPEs) are regarded as a promising alternative to conventional electrolytes, combining the advantages of solid and liquid electrolytes. Leveraging the abundance and eco-friendliness of cellulose-based materials, GPEs were produced using methyl cellulose and incorporating various doping agents, either an ionic liquid (1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide [Pyr14][TFSI]), its polymeric ionic liquid analogue (Poly(diallyldimethylammonium bis(trifluoromethylsulfonyl)imide) [PDADMA][TFSI]), or an anionically charged backbone polymeric ionic liquid (lithium poly[(4-styrenesulfonyl)(trifluoromethyl(S-trifluoromethylsulfonylimino) sulfonyl) imide] LiP[STFSI]). The ion dynamics and molecular interactions within the GPEs were thoroughly analyzed using Attenuated Total Reflectance Fourier-Transform Infrared Spectroscopy (ATR-FTIR), Heteronuclear Overhauser Enhancement Spectroscopy (HOESY), and Pulsed-Field Gradient Nuclear Magnetic Resonance Diffusion (PFG-NMR).
View Article and Find Full Text PDFSoft Matter
October 2024
Chemistry of Interfaces, Luleå Tekniska Universitet, Luleå SE-97187, Sweden.
The measurement of ion diffusivity inside nanoporous materials by Pulsed-Field Gradient (PFG) NMR is not an easy task due to enhanced NMR relaxation. Here, we employed multinuclear (H, P, and Li) NMR spectrometry and diffusometry to probe ion dynamics of a fluorine-free battery electrolyte comprising the [P][MEEA] ionic liquid (IL) and LiMEEA salt in a 7 : 3 molar ratio, confined in three different nanoporous SiO glasses with pore diameters of 3.7, 7 and 98 nm.
View Article and Find Full Text PDFBiophys J
November 2024
Structural Biology and NMR Laboratory, The Linderstrøm-Lang Centre for Protein Science, University of Copenhagen, Copenhagen, Denmark. Electronic address:
Measuring the compaction of a protein or complex is key to our understanding of the interactions within and between biomolecules. Experimentally, protein compaction is often probed either by estimating the radius of gyration (R) obtained from small-angle x-ray scattering (SAXS) experiments or the hydrodynamic radius (R) obtained, for example, by pulsed field gradient NMR (PFG NMR) spectroscopy. PFG NMR experiments generally report on the translational diffusion coefficient, which in turn can be used to estimate R using an internal standard to account for sample viscosity and uncertainty about the gradient strength.
View Article and Find Full Text PDFAdv Sci (Weinh)
November 2024
Department of Obstetrics and Gynecology, The Third Affiliated Hospital, Southern Medical University, Guangzhou, 510630, China.
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