The birefringence of MBBA, determined from the channeled spectra, decreases when the wavelength increases, showing a normal dispersion. The changes induced by an external electrostatic field acting perpendicular on the nematic director in the birefringence values were evidenced. The birefringence increases with the electrostatic field intensity which enhances the preferential alignment by the big values of the electric dipole moments induced parallel to the long MBBA molecule. The main refractive indices were interferometrically measured for three visible monochromatic radiations and the birefringence values were concordant with those estimated from the channeled spectra. The main molecular polarizabilities were estimated.
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http://dx.doi.org/10.1016/j.saa.2006.12.024 | DOI Listing |
Microscopy (Oxf)
January 2025
Department of Materials Physics, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan.
The distribution of dopants in host crystals significantly influences the chemical and electronic properties of materials. Therefore, determining this distribution is crucial for optimizing material performance. The previously developed statistical ALCHEMI (St-ALCHEMI), an extension of the atom-location by channeling-enhanced microanalysis (ALCHEMI) technique, utilizes variations in electron channeling based on the beam direction relative to the crystal orientation.
View Article and Find Full Text PDFMolecules
December 2024
Faculty of Physics, Alexandru Ioan Cuza University, 11 Carol I Blvd, RO-700506 Iasi, Romania.
A rapid and simple spectral method for determining the linear birefringence of thin anisotropic films, using the channeled spectra, is proposed in this article. Two channeled spectra must be recorded for a transparent system containing a thick anisotropic layer and a thin stretched polymer film, when the two anisotropic uniaxial layers have parallel and perpendicular optical axes, respectively. The sum and difference of the two channeled spectra indicate (by the positions of the maxima and minima in the resulting channeled spectra) the phase difference introduced by the thin polymer film.
View Article and Find Full Text PDFRSC Adv
August 2024
Department of Pharmaceutical Chemistry, College of Pharmacy, Jouf University Sakaka Aljouf 72388 Saudi Arabia.
The use of plant seed-based hydrogels to design drug delivery systems (DDSs) has increased due to their swellable, pH-responsive, biocompatible, biodegradable, and non-toxic nature. Herein, the chia seeds hydrogel (CSH) was extracted through an aqueous extraction method to explore its pH and salt-responsive swelling behavior and sustained release potential. The CSH was characterized using Fourier transform infrared (FT-IR) and solid-state cross-polarization magic angle spinning carbon-13 nuclear magnetic resonance (solid/state CP-MAS C/NMR) spectra.
View Article and Find Full Text PDFChanneled spectropolarimetry enables real-time measurement of the polarimetric spectral information of the target. A crucial aspect of this technology is the accurate reconstruction of Stokes parameters spectra from the modulated spectra obtained through snapshot measurements. In this paper, a learnable sparse dictionary compressed sensing method is proposed for channeled spectropolarimeter (CSP) spectral reconstruction.
View Article and Find Full Text PDFInt J Mol Sci
April 2024
Faculty of Physics, "Alexandru Ioan Cuza" University, 700506 Iasi, Romania.
Investigation of chiroptical polymers in the solution phase is paramount for designing supramolecular architectures for photonic or biomedical devices. This work is devoted to the case study of poly(propylene oxide) (PPO) optical activity in several solvents: benzonitrile, carbon disulfide, chloroform, ethyl acetate, and -dioxane. To attain information on the interactions in these systems, rheological testing was undertaken, showing distinct variations of the rheological parameters as a function of the solvent type.
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