AI Article Synopsis
- Several molybdenum complexes were synthesized, specifically [Mo(CO)4(N-N)], [MoCl(eta3-methallyl)(CO)2(N-N)], and [Mo(eta3-methallyl)(CNtBu)(CO2)(N-N)]BAr'4, using different ligands (N-N).
- The ligands used in these complexes include 4,4'-bis((4-methylphenyl)carbamoyl)-2,2'-bipyridine (bipy') and 2,2'-biimidazole (H2biim).
- The synthesized complexes were characterized using techniques like IR spectroscopy, 1H NMR, and X-ray diffraction
Article Abstract
Compounds [Mo(CO)4(N-N)] (N-N = 4,4'-bis((4-methylphenyl)carbamoyl)-2,2'-bipyridine, bipy', 1; or 2,2'-biimidazole, H2biim, 2), [MoCl(eta3-methallyl)(CO)2(N-N)] (N-N = bipy', 3; H2biim, 4), and [Mo(eta3-methallyl)(CNtBu)(CO2)(N-N)]BAr'4 (Ar' = 3,5-bis(trifluoromethyl)phenyl; N-N= bipy', 5; H2biim, 6) were synthesized and characterized, and their behavior toward anions was investigated in solution (IR and 1H NMR) and in solid state (X-ray diffraction).
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| http://dx.doi.org/10.1021/ic0621650 | DOI Listing |
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