Half-centimeter-high mats of vertically aligned single-walled carbon nanotubes were grown at 600 degrees C by point-arc microwave plasma chemical vapor deposition. The mats were produced from 0.5 nm of an Fe catalyst layer, thus showing one of the highest catalytic yields of approximately 105 times. The growth process shows a lack of poisoning of the catalyst, in contrast to other reports. The experimental results confirm that the growth rate is ultimately limited by the gas phase diffusion of hydrocarbon radicals.
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http://dx.doi.org/10.1021/jp067776s | DOI Listing |
Nanotechnology
December 2024
Ioffe Institute, Politekhnicheskaya st. 29, Sankt-Peterburg, 194021, RUSSIAN FEDERATION.
The processes of electrochemical deposition of Ni on vertically aligned GaAs nanowires (NWs) grown by molecular-beam epitaxy (MBE) using Au as a growth catalyst on Si(111) substrates were studied. Based on the results of electrochemical deposition, it was concluded that during the MBE synthesis of NWs the self-induced formation of conductive channels can occur inside NWs, thereby forming quasi core-shell nanowires. Depending on the length of the channel compare to the NW heights and the parameters of electrochemical deposition, the different hybrid metal-semiconductor nanostructures, such as Ni nanoparticles on GaAs NW side walls, Ni clusters on top ends of GaAs NWs, core-shell Ni/GaAs NWs, were obtained.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225002, P. R. China.
The rational design of multicomponent heterostructure is an effective strategy to enhance the catalytic activity of electrocatalysts for water and seawater electrolysis in alkaline conditions. Herein, MOF-derived nitrogen-doped carbon/nickel-cobalt sulfides coupled vertically aligned Rhenium disulfide (ReS) on carbon cloth (NC-CoNiS@ReS/CC) are constructed via hydrothermal and activation approaches. Experimental and theoretical analysis demonstrates that the strong interactions between multiple interfaces promote electron redistribution and facilitate water dissociation, thereby optimizing *H adsorption energy for the hydrogen evolution reaction (HER).
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Department of Industrial and Materials Science, Chalmers University of Technology, Göteborg, 41296, Sweden.
Thermal conductivity enhancement in polymers is vital for advanced applications. This study introduces a novel method to align hexagonal boron nitride (hBN) nanosheets within polydimethylsiloxane (PDMS) matrices using a Halbach array to create a highly uniform magnetic field. This technique achieves significant improvements in thermal conductivity by effectively aligning hBN nanosheets.
View Article and Find Full Text PDFJ Shoulder Elbow Surg
December 2024
Department of Orthopaedics, Kurashiki Central Hospital, Kurashiki, Okayama, Japan.
Background: Reverse total shoulder arthroplasty (RTSA) is considered a promising surgical procedure, and several studies have reported its advantages in improving shoulder elevation. However, patients undergoing RTSA may still experience challenges related to rotational movements. While external rotation may be improved with lateralization, internal rotation may occasionally deteriorate after RTSA.
View Article and Find Full Text PDFACS Omega
December 2024
2D Materials and Devices Laboratory, Department of Physics and Nanotechnology, SRM Institute of Science and Technology, Kattankulathur 603 203, Tamil Nadu, India.
The demand for compact energy storage devices necessitates the development of high-performance anode materials directly integrated with current collectors, minimizing or eliminating the need for binders or additives. With its layered structure and high theoretical capacity, molybdenum disulfide (MoS) is regarded as a promising anode material for lithium-ion batteries (LIBs). Here, we report chemical vapor deposition (CVD) growth of self-integrated, vertically aligned MoS nanosheets with embedded molybdenum dioxide (MoO) directly on a molybdenum foil and explore its potential as an anode material for LIBs.
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