Chemistry of enediynyl azides: activation through a novel pathway.

Chem Commun (Camb)

Bioorganic Laboratory, Department of Chemistry, Indian Institute of Technology, Kharagpur, India.

Published: February 2007

The spontaneous activation of a nonaromatic enediynyl azide under ambient conditions has been demonstrated. The aromatic enediyne followed the expected cycloaddition with the alkene in the neighbouring arm to form a stable bridged bicyclic enediyne.

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Source
http://dx.doi.org/10.1039/b612114dDOI Listing

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