We report the preparation and characterization of a novel nanocomposite adsorbent for anionic dye removal. The nanocomposite adsorbent was prepared by heterocoagulation of delaminated bentonite and layered double hydroxide (LDH) colloids. The effects of preparation conditions, LDH loading, particle size, and calcination temperature of the modified material on the physicochemical properties of this composite adsorbent have been investigated. The optimal conditions for best Reactive Yellow 2 (RY2) dye removal efficiency are a weight ratio of LDH to bentonite of 1:1, LDH particle size 100 nm, and calcination temperature 673 K. The adsorption equilibrium data can be fitted well by the widely accepted adsorption isotherm models.
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http://dx.doi.org/10.1016/j.jcis.2006.12.052 | DOI Listing |
Int J Biol Macromol
January 2025
Department of Cell and Molecular Biology, Faculty of Life Science and Biotechnology, Shahid Beheshti University, P.O. Box 19839-69411, Tehran, Iran. Electronic address:
The increasing prevalence of micropollutants like cationic and anionic dyes in wastewater creates an influential environmental challenge, mainly due to their toxic effects and persistence. Current methods often lack the efficiency and versatility to cope with a wide variety of contaminants. This study explores the modification of TEMPO-oxidized cellulose nanofibers (TOCNF) using (3-chloro-2-hydroxypropyl) trimethylammonium chloride (CHPTAC) to enhance their cationic properties.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemical Engineering, Arak University, Arak, Iran. Electronic address:
Polysaccharides such as chitosan, alginate, cellulose, and carrageenan have emerged as promising adsorbents due to their biodegradability, abundant availability, and diverse chemical functionality. These biopolymers exhibit promising performance for adsorption of a wide range of pollutants including heavy metals (e.g.
View Article and Find Full Text PDFFood Chem X
January 2025
Food Processing Research Institute, Heilongjiang Academy of Agricultural Sciences, Harbin 150086, China.
An on-site, sensitive, and cost-effective method for determining aflatoxin B1 (AFB1) in rice samples is proposed, combining magnetic solid phase extraction (MSPE) and time-resolved fluorescence immunochromatography (TRFICA) techniques. Cost-effective rice husks were carbonized and combined with nanomaterials to make magnetic nanocomposites that acted as effective adsorbents in MSPE. Under optimal conditions, the entire process was completed in 15 min with a visual detection limit of 0.
View Article and Find Full Text PDFFood Chem
January 2025
Materials Research Institute and Department of Ecosystem Science and Management, 204 Energy and the Environment Laboratory, The Pennsylvania State University, University Park, PA 16802, USA. Electronic address:
This work presents a convenient and easy-to-operate method for synthesizing the functionally integrated nanocomposite of nitrogen-doped multi walled carbon nanotube networks (N-CNTs) and cobalt 2-methylimidazole (ZIF-67) nanoparticles. The N-CNTs@ZIF-67 nanocomposite was utilized to design a novel electrochemical sensing platform for detecting gallic acid (GA). The N-CNTs@ZIF-67 modified glass carbon electrode (GCE) demonstrated high sensitivity for GA electrochemical detection (LOD: 10.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
January 2025
Chemistry Department, Faculty of Science, Damanhour University, Damanhour, Egypt.
In the current work, three adsorbent materials were developed: biochar derived from date palm fiber (C), date palm fiber biochar/chitosan nanoparticles (CCS), and biochar/chitosan nanoparticle composite supplemented with glutamine (CCSG). These compounds were used as solid adsorbents to remove As from polluted water. Several characterization approaches were used to investigate all the synthesized solid adsorbents, including thermogravimetric analysis, N adsorption/desorption isotherm, scanning electron microscopy, transmission electron microscopy (TEM), attenuated total reflectance with Fourier transform infrared, and zeta potential.
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