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Aromatic pi-systems more curved than C(60). The complete family of all indenocorannulenes synthesized by iterative microwave-assisted intramolecular arylations.
J Am Chem Soc
August 2009
Merkert Chemistry Center, Department of Chemistry, Boston College, Chestnut Hill, Massachusetts 02467-3860, USA.
Syntheses and X-ray crystal structures are reported for all seven members of the indenocorannulene family, comprising indenocorannulene, both isomers of diindenocorannulene, both isomers of triindenocorannulene, tetraindenocorannulene, and pentaindenocorannulene. With each additional indenoannulation, the pyramidalization of the trigonal carbon atoms at the hub of the corannulene increases. Five of the seven indenocorannulenes contain carbon atoms at the hub that are actually more pyramidalized than the carbon atoms of C(60).
View Article and Find Full Text PDFPentaindenocorannulene and tetraindenocorannulene: new aromatic hydrocarbon pi systems with curvatures surpassing that of C60.
J Am Chem Soc
January 2007
Merkert Chemistry Center, Department of Chemistry, Boston College, Chestnut Hill, Massachusetts 02467-3860, USA.
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