AI Article Synopsis
- The study investigates the electrical double layer formed at the interface between a room-temperature ionic liquid and water by analyzing electrocapillary curves with varying concentrations of LiCl.
- Results show that Li+ ions tend to negatively adsorb at the point of zero charge, indicating a specific interaction at the interface.
- The findings align with the Gouy's double layer model, suggesting that while Li+ and Cl- ions are present, their specific adsorption at the RTIL|W interface is minimal within a polarized potential range of about 200 mV.
Article Abstract
The structure of the electrical double layer on the aqueous solution side has been studied by measuring electrocapillary curves at the polarized interface between a room-temperature ionic liquid (RTIL), tetrahexylammonium bis(trifluoromethylsulfonyl)imide, and water (W) at different concentrations of LiCl. Thermodynamic analysis of the electrocapillary curves indicates that Li+ ions negatively adsorb at the point of zero charge. The adsorption of Li+ and Cl- ions in the polarized potential window of about 200 mV can be explained by the Gouy's double layer model, and the specific adsorption of Li+ and Cl- ions at the RTIL|W interface is negligible within the polarized potential window.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/la0623073 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
RETRACTED: Yang et al. Capacitive Behavior of Aqueous Electrical Double Layer Based on Dipole Dimer Water Model. 2023, , 16.
Nanomaterials (Basel)
December 2024
School of Physics and Electronics, Central South University, Changsha 410083, China.
The journal retracts the article titled "Capacitive Behavior of Aqueous Electrical Double Layer Based on Dipole Dimer Water Model" [...
View Article and Find Full Text PDFIntegrating 3D-printed hydrogels and polymeric nanofibers in a double-layered transdermal patch for the treatment of rheumatoid arthritis.
RSC Adv
December 2024
Nanomedicine Laboratories, Center for Materials Science, Zewail City of Science and Technology 6th of October City Giza Egypt
Patients with rheumatoid arthritis (RA), an inflammatory illness that affects the synovial joints, have a much worse quality of life. Mostly, oral or injectable formulations are used to treat RA, underscoring the critical need for an innovative medication delivery method to enhance therapeutic outcomes and patient compliance. The present study integrated 3D bioprinting and electrospinning technologies to create a unique double-layered transdermal patch (TDDP) for the treatment of RA.
View Article and Find Full Text PDFHigh activity and specificity of bacteriophage cocktails against carbapenem-resistant belonging to the high-risk clones CG258 and ST307.
Front Microbiol
December 2024
Grupo de Investigación en Microbiología Básica y Aplicada (MICROBA), Escuela de Microbiología, Universidad de Antioquia, Medellín, Colombia.
Introduction: The widespread clinical and environmental dissemination of successful clones of carbapenem-resistant (CRKP) represents a serious global public health threat. In this context, lytic bacteriophages have emerged as a promising alternative for controlling these pathogens. This study describes the biological, structural, and genomic characteristics of lytic bacteriophages against the high-risk CRKP clones CG258 and ST307 and describes their performance in combination.
View Article and Find Full Text PDFFunctionalization of Layered Double Hydroxides on Bentonite for Cesium and Iodine Retention in High-level Radioactive Waste Disposal.
Chemosphere
December 2024
Division of Advanced Nuclear Engineering, POSTECH, 77, Cheongam-ro, Nam-gu, Pohang, Korea; Division of Environmental Science & Engineering, POSTECH, 77, Cheongam-ro, Nam-gu, Pohang, Korea. Electronic address:
Bentonite is regarded as an adequate buffer material in deep geological repositories and its swelling properties serve to prevent the penetration of groundwater into the repository and to minimize the release of radionuclides. However, bentonite is rarely effective in removing anionic radionuclides due to its permanent negative surface charge. The aim of this study was to enhance the anion removal ability of bentonite by incorporating layered double hydroxides (LDH) with a high anion exchange capacity.
View Article and Find Full Text PDFDirect Evidence of Excessive Charge-Carrier-Induced Degradation in InP Quantum-Dot Light-Emitting Diodes.
ACS Appl Mater Interfaces
December 2024
Department of Electronic Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.
The limited operational lifetime of quantum-dot light-emitting diodes (QLEDs) poses a critical obstacle that must be addressed before their practical application. Specifically, cadmium-free InP-based QLEDs, which are environmentally benign, experience significant operational degradation due to challenges in charge-carrier confinement stemming from the composition of InP quantum dots (QDs). This study investigates the operational degradation of InP QLEDs and provides direct evidence of the degradation process.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!