Mg2Ru2Cl10O.16H2O.

Acta Crystallogr C

Laboratoire de Chimie Moléculaire, du Contrôle de l'Environnement et des Mesures Physico-Chimiques, Faculté des Sciences, Département de Chimie, Université Mentouri de Constantine, 25000 Constantine, Algeria.

Published: January 2007

Mg2Ru2Cl10O.16H2O {dimagnesium mu-oxo-bis[pentachlororuthenate(IV)] hexadecahydrate} crystallizes in the monoclinic system (space group P2(1)/c). The structure consists of layers of [Ru2Cl10O]4- anions, [Mg(H2O)6]2+ cations and water molecules stacked along the a axis. Only the O atom bonded to Ru occupies the 2a site with -1 symmetry. All the other atoms occupy general 4e sites. The crystal structure is stabilized by O-H...O and O-H...Cl interactions.

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Source
http://dx.doi.org/10.1107/S0108270106050839DOI Listing

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