AI Article Synopsis
- The Ruff degradation reaction has been reviewed, focusing on its mechanisms and efficiency.
- The Hofer-Moest decarboxylation mechanism is suggested as the underlying process for the Ruff degradation.
- Cu(III) is identified as the active species in the copper version of the Ruff degradation, making it the most effective variation of this reaction.
Article Abstract
The Ruff degradation reaction is critically reviewed. Based on available information, the Hofer-Moest decarboxylation mechanism is presented as the mechanism for it. Cu(III) is proposed as the active species of the copper variant of the Ruff degradation, which is the most efficient form of the reaction.
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| http://dx.doi.org/10.1016/j.carres.2006.12.002 | DOI Listing |
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