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Integrating ex situ biomimetic extraction analyses into contaminated sediment assessment and management decisions.
Integr Environ Assess Manag
January 2025
Department of Civil, Environmental, and Construction Engineering, Texas Tech University, Lubbock, TX, United States.
This study evaluated a novel ex situ passive sampling biomimetic extraction (BE) method to estimate toxic potency in sediments. Gas chromatography with flame ionization detection (GC-FID) analysis of polydimethylsiloxane fibers equilibrated with field sediments was used to quantify bioavailable polyaromatic hydrocarbons (PAHs) and other unresolved, site-specific contaminant mixtures. This method is biomimetic because contaminants partition to the fiber based on hydrophobicity and abundance, and GC-FID quantification accounts for all constituents absorbed to the fiber that may contribute to toxicity.
View Article and Find Full Text PDFExploring Pyridine-Based Schemes: A Comprehensive Review on their Synthesis and Therapeutic Applications.
Med Chem
January 2025
Department of Pharmacy, BGC Trust University Bangladesh, Chittagong 4381, Bangladesh.
Pyridine and its derivatives are six-membered aromatic rings containing nitrogen, which are abundant in nature and indispensable in studying heterocyclic chemistry. They constitute significant chemical substances with numerous applications. The application of pyridine derivatives by incorporating metals in modern medicine is growing in relevance.
View Article and Find Full Text PDFEffect of Manipulation Methods and Storage Environments on the Microstructural, Chemical, and Mechanical Properties of Calcium-Enriched Mixture Cement.
Int J Biomater
January 2025
Iranian Center for Endodontic Research, Research Institute for Dental Sciences, Shahid Beheshti University of Medical Sciences, Tehran 1983963113, Iran.
This study aimed to evaluate the impact of different manipulation methods and storage environments on the microstructural, chemical, and mechanical properties of calcium-enriched mixture (CEM) cement. Four sample groups were examined, including nondried (ND-I) and dried (D-I) groups placed directly in an incubator, dried samples stored in phosphate-buffered saline (PBS) (D-P), and dried samples stored in distilled water (D-W). Various analyses, including Vickers microhardness, compressive strength, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS) were conducted after incubating the samples for 7 days.
View Article and Find Full Text PDFEvaluation of acute plant toxicity, antioxidant activity, molecular docking and bioactive compounds of lemongrass oil isolated from Omani cultivar.
Toxicol Rep
June 2025
School of Pharmacy, College of Health Sciences, University of Nizwa, Oman.
Lemongrass (Poaceae) is one of the aromatic plants with strong odors. Traditionally, lemon grass oil has been used for the treatment of many diseases such as gastrointestinal cramps, high blood pressure, high body temperatures, and fatigue, and is also considered an antibacterial and anti-diarrheal agent. Therefore, this study aims to investigate volatile active constituents and a few important biological activities of the volatile oil of lemongrass (Cymbopogon citratus) grown in Oman.
View Article and Find Full Text PDFRealizing a 3C Fast-Charging Practical Sodium Pouch Cell.
Angew Chem Int Ed Engl
January 2025
Beihang University, 37 Xue Yuan Road, Hai Dian District, 100191, Beijing, CHINA.
Sodium-ion batteries (SIBs), endowed with relatively small Stokes radius and low desolvation energy for Na+, are reckoned as a promising candidate for fast-charging endeavors. However, the C-rate charging capability of practical energy-dense sodium-ion pouch cells is currently limited to ≤1C, due to the high propensity for detrimental metallic Na plating on the hard carbon (HC) anode at elevated rates. Here, an ampere-hour-level sodium-ion pouch cell capable of 3C charging is successfully developed via phosphorus (P)-sulfur (S) interphase chemistry.
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