A bowl-shaped phosphine as a ligand in palladium-catalyzed Suzuki-Miyaura coupling of aryl chlorides: effect of the depth of the bowl.

Org Lett

Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, CREST, Japan Science and Technology Agency (JST), Kyoto 615-8510, Japan.

Published: January 2007

[reaction: see text] Bowl-shaped phosphine ligands were found to be highly effective in Suzuki-Miyaura coupling of unactivated aryl chlorides, in which the depth of the bowl affected the catalytic activity considerably.

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Source
http://dx.doi.org/10.1021/ol0626138DOI Listing

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