The carriers of the diffuse interstellar band spectrum represent an important baryonic component of the interstellar medium (ISM) and it is expected that their identification will contribute significantly to the understanding of the chemistry and physics of interstellar clouds. It is widely held that the carriers are linked to the presence of dust grains on account of the good correlation of their strengths with interstellar reddening, so they offer an important potential route to improving our understanding of the composition and chemistry of grains and grain surfaces. In addition to the challenge of making the spectral assignments, an important current question concerns the spatial distribution and physical state of interstellar material, with recent observational atomic and molecular line absorption studies suggesting that diffuse clouds are more 'clumpy' than previously thought. We describe here high signal-to-noise optical observations made at the Anglo-Australian Telescope using UCLES that were undertaken to investigate the spatial distribution of diffuse band carriers. We describe the first detection of 'small-scale-structure' in the diffuse band carrier distribution in the ISM, and comment on the possibilities that these data hold for contributing to the solution of the diffuse band problem and our understanding of the nature of small-scale-structure in the diffuse ISM.
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Langmuir
January 2025
Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, 16846-13114 Tehran, Iran.
Carbon microspheres (CMSs) are recognized as highly effective microwave absorbers due to their exceptional wave absorption properties. In this study, 5,10,15,20-tetrakis(4-aminophenyl)porphyrin, a metamaterial, was chemically bonded to CMSs─considered a conjugated carbon structure─using a 1,3-dibromopropane linker to explore the synergistic properties and microwave absorption capabilities of the synthesized composite. The synthesized structures were characterized by using X-ray diffraction, FE-SEM, Fourier transform infrared, diffuse reflectance spectroscopy, and VNA analyses.
View Article and Find Full Text PDFDalton Trans
January 2025
Departamento de Química Inorgánica, Facultad de Química y Farmacia, Centro de Energía UC, Centro de Investigación en Nanotecnología y Materiales Avanzados CIEN-UC, Pontificia Universidad Católica de Chile, Avenida Vicuña Mackenna, 4860, Santiago, Chile.
Recalcitrant pollutants are challenging to degrade during water treatment processes. Methylene blue (MB), a cationic dye, is particularly resistant to degradation and is environmentally persistent. Heterogeneous photocatalysis has emerged as a suitable strategy for removing such pollutants from water.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 5-13, Munich 81377, Germany.
Covalent organic frameworks (COFs), crystalline and porous conjugated structures, are of great interest for sustainable energy applications. Organic building blocks in COFs with suitable electronic properties can feature strong optical absorption, whereas the extended crystalline network can establish a band structure enabling long-range coherent transport. This peculiar combination of both molecular and solid-state materials properties makes COFs an interesting platform to study and ultimately utilize photoexcited charge carrier diffusion.
View Article and Find Full Text PDFRadiother Oncol
December 2024
Section for Biomedical Physics, Department of Radiation Oncology, University of Tübingen, Tübingen, Germany; German Cancer Consortium (DKTK), partner site Tübingen, and German Cancer Research Center (DKFZ), Heidelberg, Germany; Cluster of Excellence "Machine Learning", University of Tübingen, Tübingen, Germany. Electronic address:
Purpose: To retrain a model based on a previously identified prognostic imaging biomarker using apparent diffusion coefficient (ADC) values from diffusion-weighted magnetic resonance imaging (DW-MRI) in a preclinical setting and validate the model using clinical DW-MRI data of patients with locally advanced head-and-neck cancer (HNC) acquired before radiochemotherapy.
Material And Methods: A total of 31 HNC patients underwent T2-weighted and DW-MRI using 3 T MRI before radiochemotherapy (35x2Gy). Gross tumor volumes (GTV) were delineated based on T2-weighted and b500 images.
Discov Nano
December 2024
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu, 611731, Sichuan, People's Republic of China.
LiTiO (LTO) batteries are known for safety and long lifespan due to zero-strain and stable lattice. However, their low specific capacity and lithium-ion diffusion limit practical use. This study explored modifying LTO through yttrium doping by hydrothermal method to form LiYTiO nanoparticles.
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