The evolution of the nanodomain pattern of the uniaxial relaxor ferroelectric strontium barium niobate doped with cerium was studied by piezoresponse force microscopy (PFM). The fractal-like nanodomains observed at room temperature decay on heating. At temperatures up to about 15 K above the Curie temperature, Tc = 320 K, areas of correlated polarization are still visible. On cooling from the paraelectric state to below Tc, a slow isothermal growth of nanodomain was found. The mean domain size increases according to a logarithmic law as predicted for the three-dimensional random field Ising model.
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http://dx.doi.org/10.1109/tuffc.2006.173 | DOI Listing |
Materials (Basel)
December 2023
Faculty of Science and Technology, Institute of Materials Engineering, University of Silesia in Katowice, 75 Pułku Piechoty Street 1a, 41-500 Chorzów, Poland.
In this work, were synthesized (PbLa)(ZrTi)O ceramic materials with different concentrations of praseodymium (0, 0.1, 0.3, 0.
View Article and Find Full Text PDFMaterials (Basel)
March 2023
Angewandte Physik, University of Duisburg-Essen, D-47048 Duisburg, Germany.
Uniaxial ferroelectrics with tetragonal tungsten bronze structure are important functional materials with photorefractive, electrooptic, piezoelectric, and pyroelectric properties. SrBaNbO (SBN100) with > 50 is known as a typical uniaxial relaxor ferroelectric, while CaBaNbO (CBN100) undergoes nearly normal ferroelectric phase transitions. Single crystals of CSBN100 = [(CBN28) + (1 - ) (SBN61)] = CaBaNbO + (1 - ) SrBaNbO with nominal = 0.
View Article and Find Full Text PDFMater Horiz
July 2022
Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, Ohio, 44106-7202, USA.
Although high piezoelectric coefficients have recently been observed in poly(vinylidene fluoride--trifluoroethylene) [P(VDF-TrFE)] random copolymers, they have low Curie temperatures, which makes their piezoelectricity thermally unstable. It has been challenging to achieve high piezoelectric performance from the more thermally stable PVDF homopolymer. In this report, we describe how high-power ultrasonic processing was used to induce a hard-to-soft piezoelectric transition and improve the piezoelectric coefficient in neat PVDF.
View Article and Find Full Text PDFPolymers (Basel)
March 2018
Department of Applied Chemistry, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, School of Science, Xi'an Jiaotong University, Xi'an 710049, China.
Poly(vinylidene fluoride) (PVDF) based ferroelectric polymers have attracted considerable attention both academically and industrially due to their tunable ferroelectric properties. By pinning the conformation of the polymer chain and the ferroelectric phase physically or chemically, the ferroelectric behaviors of PVDF based polymers could be finely turned from normal ferroelectric into relaxor ferroelectric, anti-ferroelectric like, and even linear dielectric. Besides high energy electron irradiation and chemical copolymerization with the bulky monomers, in this work, an alternative strategy is presented to regulate the dielectric and ferroelectric performances of PVDF based ferroelectric polymer for the first time.
View Article and Find Full Text PDFJ Phys Condens Matter
May 2019
Peter the Great Saint-Petersburg Рolytechnic University, 29 Polytechnicheskaya, 195251 St.-Petersburg, Russia.
The structure and diffuse scattering in uniaxial relaxor SrBaNbO single crystal have been studied by x-ray diffraction at room temperature. Two different kinds of local ordering with different correlation lengths and different shapes of correlation functions have been revealed. The values of correlation lengths have been determined from analysis of experimental data.
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