We extend the analysis of the effects of electromagnetic (EM) fields on mesoscopic conductors to include the effects of field quantization, motivated by recent experiments on circuit QED. We show that in general there is a photovoltaic (PV) current induced by quantized cavity modes at zero bias across the conductor. This current depends on the average photon occupation number and vanishes identically when it is equal to the average number of thermal electron-hole pairs. We analyze in detail the case of a chaotic quantum dot at temperature Te in contact with a thermal EM field at temperature Tf, calculating the rms size of the PV current as a function of the temperature difference, finding an effect approximately pA.
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http://dx.doi.org/10.1103/PhysRevLett.97.216801 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Department of Physics and Astronomy & Wright Center for Photovoltaic Innovation and Commercialization, The University of Toledo, Toledo, Ohio 43606, United States.
Wide band gap FACsPb(IBr) perovskite photovoltaic (PV) devices are measured by spectroscopic ellipsometry in the through-the-glass configuration and analyzed to determine the complex optical property spectra of the perovskite absorber as well as the structural properties of all constituent layers. This information is used to simulate external quantum efficiency (EQE) spectra, to calculate PV device performance parameters such as short circuit current density, open circuit voltage, fill factor, and power conversion efficiency, and to develop strategies for increasing the accuracy of predictions. Simulations and calculations tend to overestimate PV device performance parameters, undermining the accuracy and usefulness of those simulations.
View Article and Find Full Text PDFJ Org Chem
January 2025
Institute of Theoretical Chemistry and College of Chemistry, Jilin University, Changchun 130023, P.R. China.
Thiophene and pyrrole units are extensively utilized in light-responsive materials and have significantly advanced the field of organic photovoltaics (OPV). This progress has inspired our exploration of photosensitizers (PS) for photodynamic therapy (PDT). Currently, traditional PS face limitations in clinical application, including a restricted variety and narrow applicability.
View Article and Find Full Text PDFMater Horiz
January 2025
State Key Laboratory of Organic-Inorganic Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Solar energy sources have garnered significant attention as a renewable energy option. Despite this, the practical power conversion efficiency (PCE) of widely used silicon-based solar cells remains low due to inefficient light utilization. In this study, carbon dots (APCDs) were prepared a hydrothermal method using ammonium polyphosphate and -phenylenediamine, then incorporated into a silicone-acrylic emulsion (CAS) to create a luminescent down-shifting (LDS) layer for solar cells.
View Article and Find Full Text PDFLight trapping structures can enhance the absorption and reduce the thickness and costs of solar cells. Among light trapping structures, the metasurface structure utilizes Mie scattering to make light enter the solar active layer better, thus improving the photovoltaic conversion efficiency of solar cells. Herein, we simulated and optimized a metasurface light-trapping structure for solar cells and implemented this structure on solar cells.
View Article and Find Full Text PDFHeliyon
January 2025
Department of Electronic Engineering, University of Nigeria, Nsukka, 410001, Enugu, Nigeria.
Maximum Power Point Tracking (MPPT) is a technique employed in photovoltaic (PV) systems to ensure that the modules transfer the maximum generated power to the load. An advanced algorithm, the Improved Optimized Adaptive Differential Conductance (IOADC), was developed by applying Kirchhoff's law within a single diode model framework. The algorithm's performance was evaluated under various solar irradiance levels of 500 W/m, 750 W/m, and 1000 W/m at a constant temperature of 298K, analyzing its impact on power generation and transfer.
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