Experiments involving phase coherent dynamics of networks of spins, such as echo experiments, will only work if decoherence can be suppressed. We show here, by analyzing the particular example of a crystalline network of Fe8 molecules, that most decoherence typically comes from pairwise interactions (particularly dipolar interactions) between the spins, which cause "correlated errors." However, at very low T these are strongly suppressed. These results have important implications for the design of quantum information processing systems using electronic spins.
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http://dx.doi.org/10.1103/PhysRevLett.97.207206 | DOI Listing |
Chem Sci
June 2020
National Renewable Energy Laboratory 15013 Denver West Parkway Golden Colorado 80401 USA
In singlet fission (SF) the initially formed correlated triplet pair state, (TT), may evolve toward independent triplet excitons or higher spin states of the (TT) species. The latter result is often considered undesirable from a light harvesting perspective but may be attractive for quantum information sciences (QIS) applications, as the final exciton pair can be spin-entangled and magnetically active with relatively long room temperature decoherence times. In this study we use ultrafast transient absorption (TA) and time-resolved electron paramagnetic resonance (TR-EPR) spectroscopy to monitor SF and triplet pair evolution in a series of alkyl silyl-functionalized pentadithiophene (PDT) thin films designed with systematically varying pairwise and long-range molecular interactions between PDT chromophores.
View Article and Find Full Text PDFJ Chem Phys
September 2020
Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, USA.
Decoherence corrections increase the accuracy of mixed quantum-classical nonadiabatic molecular dynamics methods, but they typically require explicit knowledge of the potential energy surfaces of all occupied electronic states. This requirement renders them impractical for applications in which large numbers of electronic states are occupied. The authors recently introduced the collapse to a block (TAB) decoherence correction [M.
View Article and Find Full Text PDFJ Chem Phys
June 2020
Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, USA.
Independent trajectory (IT) nonadiabatic molecular dynamics simulation methods are powerful tools for modeling processes involving transitions between electronic states. Incorporation and refinement of decoherence corrections into popular IT methods, e.g.
View Article and Find Full Text PDFPhys Rev Lett
October 2017
Institut für Physik, Universität Mainz, Staudingerweg 7, 55128 Mainz, Germany.
We demonstrate the deterministic generation of multipartite entanglement based on scalable methods. Four qubits are encoded in ^{40}Ca^{+}, stored in a microstructured segmented Paul trap. These qubits are sequentially entangled by laser-driven pairwise gate operations.
View Article and Find Full Text PDFSci Rep
September 2016
College of Physics and Materials Science, Tianjin Normal University, Tianjin 300387, China.
Short-range interaction among the spins can not only results in the rich phase diagram but also brings about fascinating phenomenon both in the contexts of quantum computing and information. In this paper, we investigate the quantum correlation of the system coupled to a surrounding environment with short-range anisotropic interaction. It is shown that the decay of quantum correlation of the central spins measured by pairwise entanglement and quantum discord can serve as a signature of quantum phase transition.
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