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First enantioselective total synthesis and structure determination of the anthrapyran metabolite gamma-indomycinone. | LitMetric
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First enantioselective total synthesis and structure determination of the anthrapyran metabolite gamma-indomycinone.

Lutz F Tietze Ramakrishna Reddy Singidi Kersten M Gericke

Org Lett

Institute of Organic and Biomolecular Chemistry, Georg-August-University, Tammannstrasse 2, D-37077 Göttingen, Germany.

Published: December 2006

The first total synthesis of (R)-gamma-indomycinone has been achieved which allowed the determination of the configuration of the stereogenic center of natural gamma-indomycinone as (S). The approach stands out for its generality and efficiency. [reaction: see text]

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 Source
http://dx.doi.org/10.1021/ol062492bDOI Listing

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