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Anodic polarization tests were performed in 0.9% NaCl and 1% lactic acid solutions to characterize the relationship between the corrosion behavior and the microstructures of cast Ti-Ag (5-40% Ag) alloys. The anodic polarization curves for the Ti-Ag alloys up to 17.5% Ag were similar to those for pure titanium in both solutions. On the other hand, an abrupt increase in the current density was observed for the alloys with more than 20% Ag in the NaCl solution and with more than 27.5% Ag in the lactic acid solution. The microstructures of the corroded alloy surfaces indicated the deterioration of precipitated intermetallic compounds along the grain boundaries. The Ti-Ag alloys up to 17.5% Ag had excellent corrosion resistance similar to that of pure titanium. The alloys with 20-25% Ag may be also used as dental alloys, since they passivated again immediately after preferential dissolution in the NaCl solution.
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http://dx.doi.org/10.4012/dmj.25.516 | DOI Listing |
Clin Oral Investig
September 2023
Department of Prosthodontics, School and Hospital of Stomatology, Liaoning Provincial Key Laboratory of Oral Diseases, China Medical University, Shenyang, 110001, China.
Objectives: Surface micro-area potential difference (MAPD) can achieve bacteriostatic performance independent of metal ion dissolution. To study the influence of MAPD on antibacterial properties and the cellular response, Ti-Ag alloys with different surface potentials were designed and prepared by changing the preparation and heat treatment processes.
Materials And Methods: Ti-Ag alloys (T4, T6, and S) were prepared by vacuum arc smelting, water quenching, and sintering.
Materials (Basel)
December 2022
Division of Dental Biomaterials, Tohoku University Graduate School of Dentistry, 4-1 Seiryo-machi, Aoba-ku, Sendai 980-8575, Japan.
Titanium-20 mass% Silver (Ti-20%Ag) alloy can suppress biofilm formation on the surface. Unlike bactericidal agents, it does not kill bacteria; therefore, the healthy oral microflora remains undisturbed. To utilize the unique functions of this alloy and enable its use in the fabrication of dental prostheses that require relatively high strength, we added copper (Cu) as an alloying element to improve strength.
View Article and Find Full Text PDFMater Sci Eng C Mater Biol Appl
September 2021
Key Lab. for Anisotropy and Texture of Materials, Education Ministry of China, School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China; Research Center for Metallic Wires, Northeastern University, Shenyang 110819, China. Electronic address:
The precipitates in Ti-Ag alloy made an important contribution to antibacterial activity. In order to study this specific effects, Ti-Ag samples with different forms of precipitates were produced by powder metallurgy and ingot metallurgy followed by heat treatment: Ti-Ag(T4) with no precipitate, Ti-Ag(as-cast) and Ti-Ag(T6) with TiAg and Ti-Ag(PM) with TiAg and Ag-rich phase. Microstructure was analyzed by scanning electronic microscope (SEM), and the antibacterial effects, expression of reactive oxygen species (ROS), protein leakage and biocompatibility were investigated by plate count method, staining technology and cell test.
View Article and Find Full Text PDFIn prosthetic joint surgery, Ag coating of implant areas in direct contact with bone has been met with hesitation for fear of compromising osseointegration. The physicochemical, antibacterial and osteoconductive properties of three different Ti samples were studied: Ti6Al4V alloy that was grit-blasted (GB), Ti6Al4V alloy with an experimental Ti-Ag-nitride layer (SN) applied by physical vapour deposition (PVD) and commercially available PVD-coated Ti6Al4V alloy with a base Ag layer and a surface Ti-Ag-nitride layer (SSN, clinically known as PorAg®). Ag content on the surface of experimental SN and SSN discs was 27.
View Article and Find Full Text PDFMaterials (Basel)
November 2020
Research Center for Ultra-High Voltage Electron Microscopy, Osaka University,7-1, Mihogaoka, Ibaraki, Osaka 567-0047, Japan.
The Ti-Ag alloy system is an important constituent of dental casting materials and metallic biomaterials with antibacterial functions. The binary Ti-Ag alloy system is characterized by flat liquidus lines with metastable liquid miscibility gaps in the phase diagram. The ternary Ti-Ag-based alloys with liquid phase separation (LPS) were designed based on the mixing enthalpy parameters, thermodynamic calculations using FactSage and Scientific Group Thermodata Europe (SGTE) database, and the predicted ground state diagrams constructed by the Materials Project.
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