The surface of dried biomass of baker's yeast was modified by crosslinking cystine with glutaraldehyde. X-ray photoelectron spectroscopy and microscope were used to characterize the modified biomass. The adsorption capacity of the modified biomass for Cd(2+) and Pb(2+) showed an increase compared with the pristine biomass due to the presence of cystine on the biomass surface. Experimental data showed that the adsorption of the two metal ions increased with time until equilibrium was achieved. The adsorption capacities for Cd(2+) and Pb(2+) were 11.63 and 45.87 mg g(-1), respectively, which were determined from the Langmuir isotherm. The loaded biosorbent was regenerated using HCl solution and could be used repeatedly at six times with little loss of uptake capacity. FTIR spectroscopy revealed that carboxyl, amide, and hydroxyl groups on the biomass surface were involved in the adsorption of Cd(2+) and Pb(2+).
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http://dx.doi.org/10.1016/j.jhazmat.2006.09.021 | DOI Listing |
Environ Pollut
January 2025
College of Engineering, Nanjing Agricultural University, PR China. Electronic address:
Ecotoxicol Environ Saf
January 2025
College of Resources and Environmental Sciences, Gansu Agricultural University, Lanzhou 730070, PR China; Gansu Provincial Key Laboratory of Arid land Crop Science, Gansu Agricultural University, Lanzhou 730070, PR China. Electronic address:
The contamination of water and soil by heavy metals (HMs) is a global issue that should be given much more concern. Modified nano-zero-valent iron (nZVI) composites offer an effective strategy for HMs remediation, but few studies have focused on removing coexisting HMs and the eco-toxicity of the composite. In this study, corn straw biochar-supported nZVI composites (nZVI-BC) were synthesized, characterized and used for the removal of Cr, Pb, and Cd in single and multi-system at different composites dosages, metal concentrations, and solution pH.
View Article and Find Full Text PDFRSC Adv
January 2025
Department of Freshman Engineering, PVP Siddhartha Institute of Technology Vijayawada 520007 Andhra Pradesh India.
Assessing heavy metal ion (HMI) contamination to sustain drinking water hygiene is a challenge. Conventional approaches are appealing for the detection of HMIs but electrochemical approaches can resolve the limitations of these approaches, such as tedious sample preparation, high cost, time consuming and the need for trained professionals. Here, an electrochemical approach is developed using a nano-sphered polypyrrole (PPy) functionalized with MoS (PPy/MoS) by square wave anodic stripping voltammetry for the detection of HMIs.
View Article and Find Full Text PDFACS Omega
December 2024
School of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China.
Alkaline fusion is a pivotal process influencing the cost of synthesizing zeolite from coal gangue. This study examined the effects of alkaline fusion temperature ( ), treatment duration ( ) and the NaOH/coal gangue weight ratio ( ) on the composition and properties of the products, as well as their adsorption capacities for Cd ( ) and Pb ( ). Response surface methodology (RSM) was employed to analyze the interactions among these factors, and the adsorption mechanisms for Cd and Pb were investigated using X-ray diffraction, scanning electron microscopy-EDS, Fourier transform infrared, X-ray photoelectron spectroscopy, and N adsorption-desorption techniques.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, PR China; Engineering Research Center of Oilfield Chemistry, Ministry of Education, Chengdu 610500, PR China; Oil & Gas Field Applied Chemistry Key Laboratory of Sichuan Province, Chengdu 610500, PR China. Electronic address:
In this study, polyamide/silica/sodium alginate (SA) composite (PA-Si-SA) was successfully prepared in one-step benzoxazine-isocyanide chemistry (BIC)/sol-gel process at room temperature. The chemical structure and fundamental properties of PA-Si-SA were characterized by FT-IR, solid-state C NMR, XPS, XRD, SEM, BET and TG, etc. The presence of anionic SA and diverse N, O-containing functional segments (amide, tertiary amine, alkyl/phenol -OH, Si-O-Si, and COO) in PA-Si-SA endows it synergistic complexation capability toward Pb and Cd.
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