Here we report the detailed measurement of long-range heteronuclear spin-spin coupling constants, especially 2, 3JCH spin-spin couplings for eight different cyclopentane derivatives. These 2, 3JCH constants were shown to be a useful tool in the determination of the relative stereochemistry in these rings. The coupling constant measurements reported here are based on two different experiments: a 2D heteronuclear correlation experiment named G-BIRDR, X-CPMG-HSQMBC and the 2D-coupled gHSQC {1H-13C} experiment
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/mrc.1912 | DOI Listing |
Publication Analysis
Top Keywords
coupling constants
8
cyclopentane derivatives
8
long-range jch
4
jch heteronuclear
4
heteronuclear coupling
4
constants cyclopentane
4
derivatives report
4
report detailed
4
detailed measurement
4
measurement long-range
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!