The combined use of advanced mass spectrometry experiments, condensed-phase synthesis of serine and homoserine nitrate ester radical precursors, and high-level ab initio calculations provides a powerful way of examining the fundamental reactivity of radicals derived from peptides.
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Gas-phase regiocontrolled generation of charged amino acid and peptide radicals.
Chem Commun (Camb)
October 2006
School of Chemistry, University of Melbourne, Victoria 3010, Australia.
The combined use of advanced mass spectrometry experiments, condensed-phase synthesis of serine and homoserine nitrate ester radical precursors, and high-level ab initio calculations provides a powerful way of examining the fundamental reactivity of radicals derived from peptides.
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