When a quantum-chaotic normal conductor is coupled to a superconductor, the random-matrix theory (RMT) predicts that a gap opens up in the excitation spectrum which is of universal size E(g)(RMT) approximately 0.3 Planck/t(D), where t(D) is the mean scattering time between Andreev reflections. We show that a scarred state of long lifetime t(S)>>t(D) suppresses the excitation gap over a window DeltaE approximately 2E(g)(RMT) which can be much larger than the narrow resonance width GammaS= Planck/t(S) of the scar in the normal system. The minimal value of the excitation gap within this window is given by GammaS/2<
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http://dx.doi.org/10.1103/PhysRevLett.97.124102 DOI Listing Publication Analysis
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Molecules
January 2025
Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Science, Profsoyuznaya 70, Moscow 117393, Russia.
Multiresonant fluorophores are a novel class of organic luminophores with a narrow emission spectrum. They can yield organic light-emitting devices, e.g.
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January 2025
Aix Marseille Univ, Université de Toulon, CNRS, CPT, Marseille, France.
The thermoelectric properties of hybrid systems based on a single-level quantum dot coupled to a normal-metal/half-metallic lead and attached to a topological superconductor wire are investigated. The topological superconductor wire is modeled by a spinless p-wave superconductor which hosts both a Majorana bound state at its extremity and above gap quasiparticle excitations. The main interest of our investigation is to study the interplay of sub-gap and single-particle tunneling processes and their contributions to the thermoelectric response of the considered system.
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January 2025
School of Power and Mechanical Engineering, Wuhan University, Wuhan, Hubei, 430072, P. R. China.
Phonon modal nonequilibrium is believed to widely exist around nanoscale hotspots, which can significantly affect the performance of nano-electronic and optoelectronic devices. However, such a phenomenon has not been explicitly observed in 3D device semiconductors at the nanoscale. Here, by employing a tip-enhanced Raman thermal measurement approach, substantial phonon nonequilibrium in gallium nitride near sub-10 nm laser-excited hotspots is directly revealed for the first time.
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January 2025
Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, United States.
Modulation of singlet and triplet energy transfer from excited semiconductor nanocrystals to attached dye molecules remains an important criterion for the design of light-harvesting assemblies. Whereas one can consider the selection of donor and acceptor with favorable energetics, spectral overlap, and kinetics of energy transfer as a means to direct the singlet and triplet energy transfer pathways, it is not obvious how to control the singlet and triplet characteristics of the donor semiconductor nanocrystal itself. By doping CsPb(ClBr) nanocrystals with Mn, we have now succeeded in increasing the triplet characteristics of semiconductor nanocrystals.
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November 2024
Laboratory of Physical Chemistry, ETH Zürich, Zurich, Switzerland.
A dynamical rearrangement in the electronic structure of a molecule can be driven by different phenomena, including nuclear motion, electronic coherence or electron correlation. Recording such electronic dynamics and identifying its fate in an aqueous solution has remained a challenge. Here, we reveal the electronic dynamics induced by electronic relaxation through conical intersections in both isolated and solvated pyrazine molecules using X-ray spectroscopy.
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