Using x-ray photon correlation spectroscopy, we studied the layer fluctuations in the lamellar phase of an ionic lyotropic system. We measured the relaxation rate of in-plane (undulation) fluctuations as a function of the wave vector. Static and dynamic results obtained during the same experiment were combined to yield the values of both elastic constants of the lamellar phase (compression and bending moduli) as well as that of the sliding viscosity. The results are in very good agreement with dynamic light-scattering data, validating the use of the technique in ordered phases.
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http://dx.doi.org/10.1103/PhysRevE.74.031706 | DOI Listing |
Food Chem
December 2024
Section of Food, Biochemical, Physiological and Nutritional Sciences, Department of Pharmaceutical Sciences, University of Perugia, 06126 Perugia, Italy.
Grape pomace (GP) is recognized as a valuable source of polyphenols, prompting research into new therapeutic molecules while enhancing this by-product value. To address low stability and bioavailability issues of phenolic compounds, lamellar solids emerge as a promising approach for their loading and stabilization in food, cosmetic, and pharmaceutical applications. A solid phase adsorption procedure was developed here by comparing the properties of eight solids towards GP polyphenols.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
January 2025
Department of Materials Science and Engineering, Hong Kong Institute for Advanced Study, City University of Hong Kong, Hong Kong, China.
The strength-ductility trade-off exists ubiquitously, especially in brittle intermetallic-containing multiple principal element alloys (MPEAs), where the intermetallic phases often induce premature failure leading to severe ductility reduction. Hierarchical heterogeneities represent a promising microstructural solution to achieve simultaneous strength-ductility enhancement. However, it remains fundamentally challenging to tailor hierarchical heterostructures using conventional methods, which often rely on costly and time-consuming processing.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Institute for Complex Molecular Systems, Eindhoven University of Technology, 5600MB Eindhoven, The Netherlands.
Spontaneous phase separation of materials is a powerful strategy to generate highly defined 2D nanomorphologies with novel properties and functions. Exemplary are such morphologies in block copolymers or amphiphilic systems, whose formation can be well predicted based on parameters such as volume fraction and shape factor. In contrast, the formation of 2D nanomorphologies is currently unpredictable in materials perfectly defined at the molecular level, in which crystallinity plays a significant role.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Physical Chemistry, Beijing Advanced Innovation Center for Materials Genome Engineering, University of Science and Technology Beijing, Beijing, China.
J Chem Phys
January 2025
School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, China.
Diblock copolyelectrolytes have significant potential in applications such as solid-state single-ion conductors, but precisely controlling their nanostructures for efficient ion transport remains a challenge. In this study, we explore the phase behavior and microphase transitions of AX BY-type diblock copolyelectrolytes under alternating electric fields using coarse-grained molecular dynamics simulations. We systematically investigate the effects of various electric field features, including unipolar and bipolar square-waves, as well as offset and non-offset sine-waves, focusing on how field strength and period influence the self-assembling morphology of the copolyelectrolytes.
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