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Conformational product control in the low-temperature photochemistry of cyclopropylcarbenes. | LitMetric
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Conformational product control in the low-temperature photochemistry of cyclopropylcarbenes.

Peter S Zuev Robert S Sheridan Ronald R Sauers Robert A Moss Gaosheng Chu

Org Lett

Department of Chemistry, University of Nevada, Reno, Nevada 89557, USA.

Published: October 2006

[reaction: see text] Different conformers of two fused-ring cyclopropylchlorocarbenes are shown to undergo distinct, wavelength-selectable, photochemistry in low-temperature matrixes. Conformers with H and Cl syn give ring expansion predominantly, whereas those with H and Cl anti mainly fragment.

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http://dx.doi.org/10.1021/ol0620601DOI Listing

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