Two-color reduced-Doppler ion imaging.

J Chem Phys

Department of Chemistry, Wayne State University, Detroit, MI 48202, USA.

Published: September 2006

We demonstrate a two-color reduced-Doppler probe for ion imaging that, in many applications, offers advantages over conventional 2+1 resonance-enhanced multiphoton ionization detection. Using counterpropagating beams of two different colors, one of which is broadband 266 nm, we achieve convenient and sensitive D atom detection without the need for Doppler scanning. We demonstrate the approach using 224 nm photodissociation of DBr. This method improves the sensitivity and signal-to-noise ratio and presents advantages and opportunities for use in the other systems.

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http://dx.doi.org/10.1063/1.2353814DOI Listing

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