Little is understood about the usefulness of sulfur isotopic ratios (sigma 34S) in tree rings because the sulfur content in rings is generally insufficient for analysis using conventional methods. We present sigma 34S values of the water-soluble and the organically bound sulfur fractions in rings of coniferous trees grown in Japan, analyzed using a large-volume oxygen bomb. Comparing the sigma 34S values of the organically bound fraction in tree rings with past atmospheric sulfur concentrations and with those of their sources, we find clear evidence that the sigma 34S values of the organically bound fraction in the rings are dependent upon the values of the atmospheric sulfur sources. The evidence suggests that the sigma 34S values in tree rings are a useful chronological proxy for evaluating possible causes of past atmospheric sulfur pollution.
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http://dx.doi.org/10.1021/es060321w | DOI Listing |
ACS Appl Mater Interfaces
March 2023
Key Laboratory of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengdu 610065, China.
Conductive hydrogels are ideal for flexible sensors, but it is still a challenge to produce such hydrogels with combined toughness, self-adhesion, self-healing, anti-freezing, moisturizing, and biocompatibility properties. Herein, inspired by natural skin, a highly stretchable, strain-sensitive, and multi-environmental stable collagen-based conductive organohydrogel was constructed by using collagen (Col), acrylic acid, dialdehyde carboxymethyl cellulose, 1,3-propylene glycol, and AlCl. The resulting organohydrogel exhibited excellent tensile (strain >800%), repeatable adhesion (>10 times), self-healing [self-healing efficiency (SHE) ≈ 100%], anti-freezing (-60 °C), moisturizing (>20 d), and biocompatible properties.
View Article and Find Full Text PDFJ Chem Phys
February 2019
School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, United Kingdom.
Ground-state rotational spectra were observed for ten symmetric-top isotopologues HN⋯S=C=S, HN⋯S=C=S, HN⋯S=C=S, HN⋯S=C=S, H N⋯S=C=S, H N⋯S=C=S, H N⋯S=C=S, H N⋯S=C=S, H N⋯S=C=S, and H N⋯S=C=S, the first five in their natural abundance in a mixture of ammonia and carbon disulphide in argon and the second group with enriched NH. The four asymmetric-rotor isotopomers HDN⋯S=C=S, HDN⋯S=C=S, HDN⋯S=C=S, and HDN⋯S=C=S were investigated by using a sample composed of ND mixed with CS. Rotational constants, centrifugal distortion constants, and S nuclear quadrupole coupling constants were determined from spectral analyses and were interpreted with the aid of models of the complex to determine its symmetry, geometry, one measure of the strength of the intermolecular binding, and information about the subunit dynamics.
View Article and Find Full Text PDFJ Chem Phys
January 2010
Department of Chemistry, Faculty of Science, Niigata University, Ikarashi, Niigata 950-2181, Japan.
The C (1)B(2)-X (1)A(1) photoexcitation of SO(2) was studied to investigate excited-state dynamics and the effects of the initial vibrational state. Ultraviolet photoabsorption cross sections (sigma's) of seven isotopologues ((32)S (16)O(2), (33)S (16)O(2), (34)S (16)O(2), (36)S (16)O(2), (32)S(16)O(17)O, (32)S(16)O(18)O, (34)S(16)O(18)O) were computed using the wave packet propagation technique based on the three-dimensional potential energy surfaces of the X and C states, which were calculated using the ab initio molecular orbital configuration interaction method. Numerous wave packet simulations were carried out under the adiabatic approximation and used to calculate the sigma's of the seven isotopologues at 298 K; we concluded that the absorption spectrum of SO(2) can be reliably modeled within the adiabatic framework based on the analysis of the time evolution of the wave packet.
View Article and Find Full Text PDFEnviron Sci Technol
September 2006
Department of Chemistry and Physics of Condensed Matter, Graduate School of Science, Kyushu University, 6-10-1, Hakozaki, Higashi-ku, Fukuoka 812-0053, Japan.
The conformation of the closed circular mitochondrial DNA in cultured human cells is changed by the addition of berenil to the culture medium in such a way that the 34-S mitochondrial DNA is converted into a 29-S DNA and finally into a 24-S DNA. The superhelix density of the covalently closed 29-S mitochondrial DNA is sigma O = -1.5 times 10(-2) (turns/10 base pairs) and consequently is intermediate between the superhelix density of the 34-S DNA (sigma0 = -2.
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