Transport of organic contaminants through salinity stratified water masses. A microcosm experiment.

Chemosphere

Department of Environmental Chemistry, I.I.Q.A.B.-C.S.I.C., Jordi Girona 18-26, E-08034 Barcelona, Spain.

Published: January 2007

A salt-wedge stratified microcosm, spiked with 31 target analytes, including PCBs, organochlorine and organophosphorous pesticides, triazines, organophosphate flame retardants and caffeine (an urban wastewater molecular marker), was setup. Compound behaviour was monitored during a four week period, by sampling at six different levels of the water column, in order to understand the transport and loss processes of the different classes of chemical substances. Compound transport from one water body to the other has been positively correlated with diffusion via their molar volume. Target analytes loss has been positively correlated with evaporation via their K(H) and with degradation via their halve-lives. From these two processes, evaporation was found to be predominant using a multiparametric regression.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.chemosphere.2006.07.061DOI Listing

Publication Analysis

Top Keywords

target analytes
8
positively correlated
8
transport organic
4
organic contaminants
4
contaminants salinity
4
salinity stratified
4
stratified water
4
water masses
4
masses microcosm
4
microcosm experiment
4

Similar Publications

Background Sigma metrics, a cornerstone of quality control (QC) in manufacturing, have been increasingly adopted in analytical processes. In clinical biochemistry labs, Sigma analysis provides insights into the level of QC achieved and identifies deviations from perfection. Methods A prospective-retrospective observational study was conducted at the Central Diagnostic Laboratory of Shree Krishna Hospital between August 2021 and July 2022.

View Article and Find Full Text PDF

Intrafraction Patient Positional Uncertainty in Lung Stereotactic Ablative Radiotherapy with Abdominal Compression.

Pract Radiat Oncol

December 2024

Department of Radiation Oncology, Willis Knighton Cancer Center, 2600 Kings Highway, Shreveport, Louisiana, USA 71103 &, Department of Clinical Research, University of Jamestown, Fargo, ND, USA. Electronic address:

Purpose: Motion management presents a significant challenge in thoracic stereotactic ablative radiotherapy (SABR). Currently, a 5.0 mm standard planning target volume (PTV) margin is widely used to ensure adequate dose to the tumor.

View Article and Find Full Text PDF

Environmental DNA to track endangered Gobiobotia naktongensis: Assessment of distribution and habitat requirements.

Sci Total Environ

December 2024

Restoration Research Team (Fishes/Amphibians & Reptiles), Research Center for Endangered Species, National Institute of Ecology, Yeongyang 36531, Republic of Korea. Electronic address:

Because of their noninvasive nature and high detection sensitivity, eDNA-based aquatic ecosystem surveys are useful for monitoring rare, elusive indicator species. Advancements in statistical techniques have expanded their use beyond simple population tracking to predict potential habitats based on the environmental conditions of sites detected eDNA. This study used species-specific molecular marker and targeted qPCR techniques to assess the distribution and habitat requirements of the endangered Gobiobotia naktongensis, a flagship fish species in Korean sandy river systems with increased public interest related to habitat restoration evaluations associated with dam construction.

View Article and Find Full Text PDF

Physicochemical characteristics of chitosan molecules: Modeling and experiments.

Adv Colloid Interface Sci

December 2024

Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Niezapominajek 8, PL-30239 Krakow, Poland. Electronic address:

Chitosan, a biocompatible polysaccharide, finds a wide range of applications, inter alia as an antimicrobial agent, stabilizer of food products, cosmetics, and in the targeted delivery of drugs and stem cells. This work represents a comprehensive review of the properties of chitosan molecule and its aqueous solutions uniquely combining theoretical modeling and experimental results. The emphasis is on physicochemical aspects which were sparsely considered in previous reviews.

View Article and Find Full Text PDF

Reliable and sensitive analytical platform to assess dietary exposure of pigs to mycotoxins and explore potential urinary biomarkers.

Talanta

December 2024

Department of Analytical Chemistry, Faculty of Chemistry, University of Murcia, Regional Campus of International Excellence "Campus Mare Nostrum", E-30100, Murcia, Spain.

A reliable and sensitive analytical platform is proposed for the assessment of pig exposure to mycotoxins through the consumption of commercial feed. A total of 48 naturally contaminated feed and 55 urine samples collected from eight Spanish farms were analyzed using a fast and simple methodology based on solid-liquid extraction (SLE) or liquid-liquid extraction (LLE) and dispersive liquid-liquid microextraction (DLLME). High-performance liquid chromatography coupled to tandem mass spectrometry (HPLC-MS/MS) was used for the targeted analysis of 27 mycotoxins from different families in both matrices achieving limits of quantification in a range of 0.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!