Study on the reactivity of diarylmethane derivatives in supercritical alcohols media: reduction of diarylmethanols and diaryl ketones to diarylmethanes using supercritical 2-propanol.

Chem Pharm Bull (Tokyo)

Department of Chemistry and Chemical Engineering, Faculty of Engineering, Yamagata University, Jonan, Yonezawa 992-8510, Japan.

Published: September 2006

We found that diarylmethanols and diaryl ketones were smoothly reduced to the corresponding diarylalkanes using supercritical 2-propanol in good yields. Furthermore, we determined the specific reaction of fluorene using supercritical methanol at high temperature.

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http://dx.doi.org/10.1248/cpb.54.1304DOI Listing

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