Synthesis of a red iron oxide/montmorillonite pigment in a CO2-rich brine solution.

J Colloid Interface Sci

UMR-G2R 7566 UHP-CNRS-INPL-CREGU, BP 239, 54506 Vandoeuvre-les-Nancy Cedex, France.

Published: November 2006

The homoionic calcium-montmorillonite was used to synthesize a red iron oxide/clay pigment in a CO2-rich brine solution (0.5 M of NaCl) by using an agitated batch-reactor (engineer autoclave). The operating conditions were 15 days of reaction, 200 bars of pressure and 150 degrees C of temperature. SEM/EDS, STEM/EDS, XRD and Infrared Spectrometry were performed to characterize before and after reaction the solid phase. The results showed the precipitation of spherical nanoparticles (50-500 nm) of iron oxide (Fe2O3) dispersed and/or coagulated in the clay-matrix. Evidently, this oxide produced red coloration in the final product. For this case, the Fe3+ cation was provided to the aqueous solution by the dissolution of Ca-montmorillonite, particularly, the dissolution of most fine particles contained in the starting clay material. The cation exchange process and precipitation of polymorph silica were also observed.

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http://dx.doi.org/10.1016/j.jcis.2006.07.064DOI Listing

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