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Synthesis and stereochemical confirmation of the secoiridoid glucosides nudiflosides D and A. | LitMetric
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Synthesis and stereochemical confirmation of the secoiridoid glucosides nudiflosides D and A.

Stephen Hanessian Emily Mainetti Fabien Lecomte

Org Lett

Department of Chemistry, Université de Montréal, C.P. 6128, Succursale Centre-ville, Montréal, Québec H3C 3J7 Canada.

Published: August 2006

We describe herein an efficient access to the highly substituted cyclopentane unit present in the Nudifloside secoiridoid family via crotyl phosphonamide anion mediated conjugate addition to cyclopentenone.

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 Source
http://dx.doi.org/10.1021/ol0615230DOI Listing

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