The aim of this study was to compare the effects of various porcelain surface-conditioning techniques, used either alone or in combination, on the shear bond strength (SBS) of ceramic brackets cured with a light emitting diode (LED). Thirty glazed porcelain facets were randomly divided into three groups of 10. In group I, the porcelain surfaces were etched with 9.6 per cent hydrofluoric acid (HFA) for 2 minutes before silane application, in group II, the porcelain surfaces were sandblasted with aluminium oxide particles, etched with 9.6 per cent HFA for 2 minutes, and silane applied, and in group III, the porcelain surfaces were sandblasted with aluminium oxide particles before silane application. Spirit ceramic brackets were bonded with a light-cured composite resin (Light Bond) and a LED. All specimens were stored in distilled water at 37 degrees C for 24 hours and thermocycled. Bond strength was determined in shear mode at a crosshead speed of 0.5 mm/minute until fracture occurred. Analysis of variance indicated a significant difference between groups (P < 0.001). The lowest SBS was found in group III (5.46 +/- 1.34, P < 0.001). No significant difference was found between group I (11.38 +/- 1.65) and group II (10.45 +/- 1.15; P > 0.05). Surface treatment with HFA and a silane coupling agent produced the highest bond strength. Sandblasting before HFA and silane application did not significantly increase bond strength. Silane application to sandblasted porcelain provided poor results in vitro and clinical trials are needed to determine its reliability for bonding ceramic brackets to ceramic crowns.
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http://dx.doi.org/10.1093/ejo/cjl026 | DOI Listing |
J Phys Chem A
January 2025
Shandong Province Key Laboratory of Medical Physics and Image Processing Technology, School of Physics and Electronics, Shandong Normal University, Jinan 250014, China.
The strategy of designing efficient room-temperature phosphorescence (RTP) emitters based on hydrogen bond interactions has attracted great attention in recent years. However, the regulation mechanism of the hydrogen bond on the RTP property remains unclear, and corresponding theoretical investigations are highly desired. Herein, the structure-property relationship and the internal mechanism of the hydrogen bond effect in regulating the RTP property are studied through the combination of quantum mechanics and molecular mechanics methods (QM/MM) coupled with the thermal vibration correlation function method.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Institute of Atomic and Molecular Physics, Jilin University, Changchun 130012, China.
This study investigates the equilibrium geometries of four different Se isomers using the coupled cluster single and double perturbative (CCSD(T)) method, extrapolating to the complete basis sets. The ground-state geometry of the Se isomer with the C structure (2.8715 Å, 2.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Pediatric Dentistry Faculty of Dental Medicine, University of Damascus, Damascus, Syria.
This in vitro study aims to evaluate various surface treatments on the shear bond strength and failure mode of CAD/CAM PMMA teeth to the heat-polymerized acrylic denture base. The study sample consisted of 100 teeth that were divided equally into five groups: Group 1: denture artificial teeth (control), Group 2: PMMA teeth without surface treatment, Group 3: PMMA teeth with MMA etching, Group 4: PMMA teeth with sandblasting (aluminum oxide particles), and Group 5: PMMA teeth with perpendicular grooves. The shear bond strength test was performed using a universal testing machine and the failure mode was recorded.
View Article and Find Full Text PDFAAPS PharmSciTech
January 2025
Xiangya School of Pharmaceutical Science, Central South University, Changsha, 410006, Hunan, China.
Acrylic pressure-sensitive adhesives (PSAs) are widely applied in transdermal drug delivery systems (TDDS). However, the molecular mechanisms underlying the effect of functional groups of PSAs on drug release and transdermal permeation properties remain insufficiently clear. In this study, we investigated the effect of acrylic PSAs' functional groups on the in vitro release and transdermal permeation properties of a model drug guanfacine (GFC).
View Article and Find Full Text PDFJ Prosthodont Res
January 2025
Institute of Dentistry, Department of Biomaterials Science and Turku Clinical Biomaterials Centre - TCBC, Turku, Finland.
Purpose: This study investigated the bond strength between short fiber-reinforced resin composite (SFC) and dentin following air abrasion with various types of abrasive particles.
Methods: A total of 120 human molars were prepared for a shear bond strength (SBS) test of the resin composite. The teeth were divided into 12 groups (n = 10/group) based on the air abrasion particle used.
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