Performing fluorescence wide-field microscopy we have imaged single semiconductor quantum dots deep inside a 3-dimensional photonic crystal prepared from colloidal polymer beads. Exploring the emission diffraction patterns in defocused images of quantum dots we demonstrate that the direction-dependent photonic stop band imprints an anisotropy to the angular emission of a single quantum dot. Hence a single, quasi-point-like emitter is manipulated to radiate its photons only to certain well-defined directions by means of the anisotropic light propagation in photonic crystals. The experiments thus provide new routes to evaluate local, frequency selective optical properties in 3-dimensional photonic crystals employing single emitters.
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http://dx.doi.org/10.1103/PhysRevLett.96.243902 | DOI Listing |
Environ Sci Pollut Res Int
January 2025
Biofuel Laboratory, Department of Energy, Tezpur University, Assam, 784028, India.
Agro-processing industries generate a substantial quantity of biomass wastes. Conversion of these wastes into valuable material could be profitable considering both environmental and economic aspects. Among various biomass conversion methods, hydrothermal conversion can be used for co-production of biofuel and other valuable materials like carbon quantum dots (CQDs) and activated carbons.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
McKetta Department of Chemical Engineering and Texas Material Institute, The University of Texas at Austin, Austin, Texas 78712, United States.
Germanium (Ge) colloidal quantum dots (CQDs) were synthesized by thermal decomposition of GeI using capping ligand mixtures of oleylamine (OAm), octadecene (ODE), and trioctylphosphine (TOP). Average diameters could be tuned across a wide range, from 3 to 18 nm, by adjusting reactant concentrations, heating rates, and reaction temperatures. OAm promotes decomposition of GeI to Ge and serves as a weakly bound capping ligand.
View Article and Find Full Text PDFAnal Methods
January 2025
School of Public Health, Hebei Medical University, Shijiazhuang, 050017, P.R. China.
In this study, a molecularly imprinted electrochemical sensor (MIECS) was constructed based on the combination of graphene quantum dots-gold nanoparticles (GQDs-AuNPs), molecular imprinting polymer (MIP), and electrochemical technology for the ultra-sensitive detection of 17β-estradiol (E). GQDs-AuNPs were synthesized and modified on the surface of glassy carbon electrodes (GCE). Safranine T was used as the functional monomer and E was the template molecule for self-assembly and electropolymerization, thus generating an MIP film on the electrode surface.
View Article and Find Full Text PDFJ Drug Target
January 2025
The Biotechnology and Drug Development Research Laboratory, Curtin Medical School & Curtin Health Innovation Research Institute, Curtin University, Bentley, Western Australia, Australia.
Vision loss and blindness are significant issues in both developed and developing countries. There are a wide variety of aetiologies that can cause vision loss, which are outlined in this review. Although treatment has significantly improved over time for some conditions, nearly half of all people with vision impairment are left untreated.
View Article and Find Full Text PDFSmall Methods
January 2025
Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei, 10607, Taiwan.
Electrochemical water splitting is a pivotal process for sustainable hydrogen energy production, relying on efficient hydrogen evolution reaction (HER) catalysts, particularly in acidic environments, where both high activity and durability are crucial. Despite the favorable kinetics of platinum (Pt)-based materials, their performance is hindered under harsh conditions, driving the search for alternatives. Due to their unique structural characteristic, Prussian blue analogs (PBAs) emerge as attractive candidates for designing efficient HER electrocatalysts.
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