Petrols with different octane numbers, diesel fuel and solutions of crude oil in toluene have been studied by the methods of absorption spectroscopy, circular dichroism spectroscopy and correlation spectroscopy of scattered light. Circular dichroism signal was registered for crude oil solutions in the spectral ranges corresponding to the measured earlier resonance absorption of asphaltene solutions in toluene. We show that the optical activity of crude oil solutions is due to the aggregation of asphaltene molecules in one spectral range and is intensified with the aggregation of asphaltene molecules in another spectral range. Petrols have no optical activity. The optical activity registered for diesel fuel is possibly due to the aggregation of asphaltene molecules.
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http://dx.doi.org/10.1016/j.jcis.2006.07.040 | DOI Listing |
J Am Chem Soc
January 2025
Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310058, P. R. China.
Purifying methane from natural gas using adsorbents not only requires the adsorbents to possess excellent separation performance but also to overcome additional daunting challenges such as humidity interference and durability requirements for sustainable use. Herein, porous organic crystals of a new macrocycle () with superhydrophobic and self-healing features are prepared and employed for the purification of methane (>99.99% purity) from ternary methane/ethane/propane mixtures under 97% relative humidity.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong, Kowloon 999077, China.
Heterogeneous ice nucleation is a widespread phenomenon in nature. Despite extensive research on ice nucleation near biological antifreeze proteins, a probe for ice nucleation and growth processes at the atomic level is still lacking. Herein, we present simulation evidence of the heterogeneous ice nucleation process on the ice-binding surface (IBS) of the antifreeze protein (TmAFP).
View Article and Find Full Text PDFClin Auton Res
January 2025
Department of Neuroscience, Mayo Clinic, Jacksonville, FL, USA.
Purpose: This study examined occupational histories in multiple system atrophy to identify environmental associations of potential relevance to disease causation.
Methods: A total of 270 neuropathologically confirmed cases of multiple system atrophy obtained from the Mayo Clinic Brain Bank for neurodegenerative disorders in Jacksonville, Florida, were included in this case-control study. Demographic and disease information was collected from medical records.
Cureus
December 2024
Department of Anatomy, A.T. Still University of Health Sciences - Kirksville College of Osteopathic Medicine, Kirksville, USA.
Erythema multiforme major (EMM) is an acute, immune-mediated mucocutaneous disease that rarely affects the genital mucosal surfaces. This study describes a 39-year-old male with this rare disease and unusual presentation. The patient presented to an emergency department with oral lesions, drainage from both eyes, injected sclera, and characteristic targetoid lesions on the face, upper extremities, torso, and plantar surfaces of the feet.
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December 2024
Information and Computer Science Department, King Fahad University of Petroleum and Minerals, Dhahran, Saudi Arabia.
Given the integration of color emotion space information from multiple feature sources in multimodal recognition systems, effectively fusing this information presents a significant challenge. This article proposes a three-dimensional (3D) color-emotion space visual feature extraction model for multimodal data integration based on an improved Gaussian mixture model to address these issues. Unlike traditional methods, which often struggle with redundant information and high model complexity, our approach optimizes feature fusion by employing entropy and visual feature sequences.
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