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Carbonyl-metal fragment insertion into eight-vertex [closo-1-CB7H8]-. Facile synthesis of ten-vertex metalladicarbollide complexes [2,2,2-(CO)3-1-OH-closo-2,1,10-MC2B7H8]n-{M = Fe, Ru (n= 0), Mn, Re (n= 1)}. | LitMetric
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Carbonyl-metal fragment insertion into eight-vertex [closo-1-CB7H8]-. Facile synthesis of ten-vertex metalladicarbollide complexes [2,2,2-(CO)3-1-OH-closo-2,1,10-MC2B7H8]n-{M = Fe, Ru (n= 0), Mn, Re (n= 1)}.

Andreas Franken Peng Lei Thomas D McGrath F Gordon A Stone

Chem Commun (Camb)

Department of Chemistry and Biochemistry, Baylor University, Waco, Texas 76798-7348, USA.

Published: August 2006

Insertion of {M(CO)4} fragments (M = Fe, Ru, Mn, Re) into the eight-vertex monocarborane anion [closo-1-CB7H8]- affords ten-vertex metal-dicarbollide complexes.

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 Source
http://dx.doi.org/10.1039/b607768dDOI Listing

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