Eu(III) dithiocarbamate complex and N-p-tolylsulfonylphenylalanine as a novel chiral catalyst for the asymmetric synthesis of cyanohydrins.

Chem Commun (Camb)

Departamento de Química Fundamental, Universidade Federal de Pernambuco, 50740-540 Recife/PE, Brazil.

Published: August 2006

The use of a new chiral lanthanide complex derived from a europium dithiocarbamate complex and a N-tosylated amino acid for the asymmetric synthesis of cyanohydrins is described. In some cases, high enantioselectivities were observed.

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http://dx.doi.org/10.1039/b607741mDOI Listing

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