Undulatory delamination of thin polymer films on gold surfaces.

J Phys Chem B

Department of Chemistry, Stanford University, Stanford, California 94305, USA.

Published: October 2005

Using two-dimensional surface plasmon resonance measurements, we have observed the formation of traveling waves in the delamination of thin films of polydimethylsilane (PDMS) exposed to methanol. Films were spin-coated on a gold surface and the methanol was added to the top surface. The stress-induced instability caused by the swelling of the PDMS thin film when its edge is pinned to the gold surface leads to wrinkle formation and propagation at the interface. The periodic pattern is thought to be the result of an Asaro-Tiller-Grinfeld (ATG) instability.

Download full-text PDF

Source
http://dx.doi.org/10.1021/jp0535644DOI Listing

Publication Analysis

Top Keywords

delamination thin
8
gold surface
8
undulatory delamination
4
thin polymer
4
polymer films
4
films gold
4
gold surfaces
4
surfaces two-dimensional
4
surface
4
two-dimensional surface
4

Similar Publications

High Areal Loading Silicon Nanoparticle-Based Lithium-Ion Batteries.

ACS Appl Mater Interfaces

January 2025

Electrical & Computer Engineering Department, Montana State University, Bozeman, Montana 59717, United States.

Interfacial mechanical stability between silicon (Si) and the current collector is crucial when high areal-loading of Si is demanded as intense stress develops at the interface due to its extreme volume alteration during the lithiation-delithiation process. Therefore, we propose using a thin, rough, porous, and highly conductive carbon nanotube network (CNT-N) as a buffer layer between the Si and current collector that provides abundant anchor sites for Si nanoparticles. The strong and elastic CNT-N, which is not involved directly in the lithiation process, reduces stress at interfaces between the Si and CNT-N and the CNT-N and current collector.

View Article and Find Full Text PDF

Flaky sputtered silicon MWCNTs core-shell structure as a freestanding binder-free electrode for lithium-ion battery.

Sci Rep

January 2025

Nano-fabricated Energy Devices Lab, School of Electrical and Computer Eng., University of Tehran, 14395-515, Tehran, Iran.

Core-shell silicon/multiwall carbon nanotubes are one of the most promising anode candidates for further improvement of lithium-ion batteries. Sufficient accommodation for massive volume expansion of silicon during the lithiation process and preventing pulverization and delamination with easy fabrication processes are still critical issues for practical applications. In this study, core-shell silicon/MWCNTs anode materials were synthesized using a facile and controllable PECVD technique to realize aligned MWCNTs followed by a silicon sputtering step.

View Article and Find Full Text PDF

Soft capacitive sensors are widely utilized in wearable devices, flexible electronics, and soft robotics due to their high sensitivity. However, they may suffer delamination and/or debonding due to their low interfacial toughness. In addition, they usually exhibit a small measurement range resulting from their limited stiffness variation range.

View Article and Find Full Text PDF

Adhesion at the interface between dissimilar materials in the semiconductor industry is an important topic, but reliable quantitative methods for strongly adhesive or highly plastic layers are hardly available. This study aims to investigate the suitability of the cross-sectional nanoindentation (CSN) method for determination of the critical energy release rate of thin film stacks in the presence of a polyimide layer as a representative structure for such a case. For this purpose, the adhesion of a deliberately weakened Si/SiO interface in a Si/SiO/Al/SiN/polyimide stack is examined by systematic variation of the experimental parameters.

View Article and Find Full Text PDF

X-ray absorption spectroscopy (XAS) is a powerful technique that provides information about the electronic and local geometric structural properties of newly developed electrocatalysts, especially when it is performed under operating conditions (i.e., ).

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!