Cavity ringdown spectra of the A-X electronic transition of the 1-propyl and 2-propyl peroxy radicals are reported. Spectroscopic assignments are facilitated by implementing several production mechanisms, either isomer-specific or not. Assignments of specific spectral lines to particular conformers of a given isomer are suggested. Observations on the temporal decay of the various species are reported.

Download full-text PDF

Source
http://dx.doi.org/10.1021/jp0457850DOI Listing

Publication Analysis

Top Keywords

a-x electronic
8
electronic transition
8
cavity ringdown
8
observation a-x
4
transition 1-c3h7o2
4
1-c3h7o2 2-c3h7o2
4
2-c3h7o2 radicals
4
radicals cavity
4
ringdown spectroscopy
4
spectroscopy cavity
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!