[Study of luminescence properties of nano-size ZnO embedded in SiO2 layer grown by radio-frequency magnetron sputtering].

Guang Pu Xue Yu Guang Pu Fen Xi

Key Laboratory of Luminescence and Optical Information, Ministry of Education, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China.

Published: March 2006

AI Article Synopsis

  • Researchers grew nano-sized ZnO embedded in SiO2 layers using radio-frequency magnetron sputtering.
  • The optical properties were analyzed through absorption and PL (Photoluminescence) spectra at room temperature, showing a blue shift in absorption as the size of ZnO decreased, indicating a stronger quantum size effect.
  • PL spectra revealed two emission peaks at 387 nm (UV emission from free-excitons) and 441 nm (blue emission from oxygen vacancy transitions), with further confirmation from time-resolved spectra and luminescence decay curves.

Article Abstract

Nano-size ZnO embedded in SiO2 layers were grown by radio-frequency magnetron sputtering. Absorption spectra and PL spectra were employed to study the optical character of the samples at room temperature. Absorption spectra blue-shifted when the size of nano-meter ZnO decreased, which indicated that quantum size effect became stronger with decreasing the size of ZnO. PL spectra show two peaks at about 387 and 441 nm, respectively. It was concluded that the UV emission originates from the radiative recombination of free-exciton, and the blue emission is due to the electron transition from donor levels of oxygen vacancies to the top of valence band. The origin of the two peaks is demonstrated by time-resolved spectra and luminescence decay curve.

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