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Synthesis, structure, and properties of a dimeric chromium(II) pyrazolato complex with a long chromium-chromium distance. Maintenance of a dimeric structure in solution and interconversion between dimeric and monomeric structures. | LitMetric
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Synthesis, structure, and properties of a dimeric chromium(II) pyrazolato complex with a long chromium-chromium distance. Maintenance of a dimeric structure in solution and interconversion between dimeric and monomeric structures.

Oussama M El-Kadri Mary Jane Heeg Charles H Winter

Inorg Chem

Department of Chemistry, Wayne State University, Detroit, Michigan 48202, USA.

Published: July 2006

The synthesis, solid-state structure, and solution structure of Cr2(tBu2pz)4 are described. This complex is obtained by sublimation of the monomeric species Cr(tBu2pz)2(4-tBupy)2 and contains long chromium-chromium distances that are enforced by the divergent nature of the pyrazolato ligands.

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http://dx.doi.org/10.1021/ic060749wDOI Listing

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