Surgical complications are the leading cause of pancreatic graft loss among diabetic patients who undergo pancreas transplantation alone (PTA), or combined with kidney transplantations (PK) or after kidney transplantations (PAK). Therapeutic effects on secondary complications of diabetes justify pancreas retransplantation (re-PT) when the first graft is lost. However, the appropriate timing for retransplant and related problems is not known. We present our initial experience on re-PT performed on seven diabetic patients who lost their first pancreas grafts (PK) due to surgical complications (venous thrombosis in five and enteric fistula in two). Five re-PT were performed a few days after the first PT without a second course of induction therapy, while two patients received re-PT some months later with reinduction therapy. In the early re-PT group, one patient died some hours after the second surgical procedure due to pulmonary embolism, while four patients lost their second grafts due to accelerated rejection within 2 years from re-PT. In the late re-PT group, both patients have good graft function without signs of rejection. Our initial experience showed discouraging results in the group of early re-PT, due to accelerated rejection episodes leading to a high incidence of graft loss. Late re-PT accompanied by reinduction therapy seemed to have better results.
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http://dx.doi.org/10.1016/j.transproceed.2006.02.136 | DOI Listing |
Nat Commun
January 2025
College of Energy, Xiamen University, Xiamen, China.
The lack of high-efficiency platinum (Pt)-based nanomaterials remains a formidable and exigent challenge in achieving high formic acid oxidation reaction (FAOR) and membrane electrode assembly (MEA) catalysis for direct formic acid fuel cell (DFAFC) technology. Herein, we report 16 Pt-based heterophase nanotrepang with rare earth (RE)-doped face-centered cubic Pt (fcc-Pt) and trigonal Pt-tellurium (t-PtTe) configurations ((RE-Pt)-PtTe HPNT). Yttrium (Y) is identified as the optimal dopant, existing as single sites and clusters on the surface.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2024
Technische Universität Berlin, Straße des 17. Juni 124, 10623 Berlin, Germany.
Despite its well-known nobility, even platinum is subject to corrosion under the harsh conditions that many technical applications require. Based on the assumption that the platinum loss is mainly caused by the formation of volatile PtO, alloying is a promising strategy to reduce it. This investigation explores the bulk stability of Pt-Au, Pt-Ir, Pt-Re, Pt-W, Pt-Ag, Pt-Rh, Pt-Cu, Pt-Ni and Pt-Co, as well as their oxides, utilizing density functional theory, as well as and literature thermodynamic data.
View Article and Find Full Text PDFDalton Trans
September 2024
School of Chemistry, Cardiff University, Cardiff, Wales, UK, CF10 3AT.
Controlled formation of mixed-metal bimetallics was achieved two derivatised 1,10-phenanthroline ligands bearing an imino- or amino-phosphine appendage at the 5-position. Selective coordination of the phen group to the [Re(CO)Cl] core was achieved enabling precise construction of bimetallic complexes with a second rhenium centre or with gold. The mixed Ru/Au complex was similarly obtained with the imino-phosphine but access to the heterobimetallic iridium systems required prior formation of the P-bound gold complexes subsequent to the introduction of the [Ir(Ppy)] fragment.
View Article and Find Full Text PDFPhys Chem Chem Phys
June 2024
Instituto de Física, Universidad Nacional Autónoma de México, Apartado Postal 20-364, Ciudad de México 01000, Mexico.
Activation of O by subnanometer metal clusters is a fundamental step in the reactivity and oxidation processes of single-cluster catalysts. In this work, we examine the adsorption and dissociation of O on RePt ( + = 5) clusters supported on rutile TiO(110) using DFT calculations. The adhesion energies of RePt clusters on the support are high, indicating significant stability of the supported clusters.
View Article and Find Full Text PDFJ Chem Phys
February 2024
Department of Physics, North Carolina State University, Raleigh, North Carolina 27695-8202, USA.
We construct correlation-consistent effective core potentials (ccECPs) for a selected set of heavy atoms and f elements that are currently of significant interest in materials and chemical applications, including Y, Zr, Nb, Rh, Ta, Re, Pt, Gd, and Tb. As is customary, ccECPs consist of spin-orbit (SO) averaged relativistic effective potential (AREP) and effective SO terms. For the AREP part, our constructions are carried out within a relativistic coupled-cluster framework while also taking into account objective function one-particle characteristics for improved convergence in optimizations.
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