1,2-Bis-[2-(5-H/Me/Cl/NO2)-1H-benzimidazolyl]-1,2-ethanediols (L1-L4), 1,4-bis-[2-(5-H/Me/Cl)-1H-benzimidazolyl]-1,2,3,4-butanetetraols (L5-L7) and their complexes with ZnCl2, CdCl2 and HgCl2 were synthesized and antibacterial activity of the compounds was tested toward Staphylococcus aureus, S. epidermidis, Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa, Salmonella typhi, Shigella flexneri, Proteus mirabilis and antifungal activity against Candida albicans. HgII complexes have a considerably higher antimicrobial activity against all microorganisms. Some HgII complexes show higher antifungal activity than clotrimazole toward C. albicans. Zn2(L3)Cl4, Zn2(L4)Cl4, and Cd(L3)Cl2 were moderately effective against S. aureus and S. epidermidis; Cd(L4)Cl2 exhibited a weak activity only against S. epidermidis.
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http://dx.doi.org/10.1007/BF02931432 | DOI Listing |
J Colloid Interface Sci
January 2025
College of Environmental Science and Engineering, Yangzhou University, Yangzhou 225000 PR China; Jiangsu Collaborative Innovation Center for Solid Organic Waste Resource Utilization, Nanjing 210095 PR China; Institutes of Agricultural Science and Technology Development, Yangzhou 225127 Jiangsu, PR China.
In this work, UiO-66-l-cys with enhanced adsorption capacity for Hg(Ⅱ) in water was synthesized through a facile two-step partial ligand replacement strategy. The presence of the functional groups significantly enhanced the capacity of the material for Hg(Ⅱ). According to the Langmuir model, the maximum theoretical adsorption capacity was calculated to be 1321.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
State Key Lab of Geohazard prevention & Geoenvironment protection, College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China. Electronic address:
Sulfur nanoparticles (SNPs) and their composites are promising for heavy metal adsorption, yet current SNPs often lack surface S, leading to low affinity toward heavy metal and ease of aggregation. Here, we report a simple light-driven method for facile prepare SNPs with surfaces enriched with S and in-situ load them onto graphene oxide (GO) to fabricate GO-S composites. Under illumination, the O generated by photosensitizer phloxine B was able to oxidize S into elemental SNPs.
View Article and Find Full Text PDFLangmuir
January 2025
Materials Science and Technology Division, CSIR─National Institute for Interdisciplinary Science and Technology, Pappanamcode, Thiruvananthapuram 695019, Kerala, India.
Mercury contamination of the environment is extremely hazardous to human health because of its significant toxicity, especially in water. Biomass-derived fluorophores such as carbon dots (CDs) have emerged as eco-friendly and cost-effective alternative sensors that provide comparable efficacy while mitigating the environmental and economic drawbacks of conventional methods. In this work, we report the fabrication of a selective fluorescence-enhancing sensor based on sulfur-doped carbon dots (SCDs) using waste bamboo-derived cellulose and sodium thiosulfate as the soft base dopant, which actively complexes with mercury ions for detection.
View Article and Find Full Text PDFSmall
December 2024
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006, China.
Developing Ag-based surface-enhanced Raman spectroscopy (SERS) sensors for detecting Hg(II) has garnered significant research interest due to their unparalleled selectivity, which is brought by the specific Ag-Hg amalgamation reaction. However, existing sensors perform unsatisfactorily in the trace detection of Hg(II) because the low concentration of Hg(II) does not have the redox potential sufficient to amalgamate with Ag. To address this challenge, a plasmonic MOF SERS sensor is developed, nanoetched Ag@UiO-68-SMe, by integrating the enormous Raman enhancement effects of nanoetched Ag with the selective enrichment function of UiO-68-SMe into single entity.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
LAQV-REQUIMTE, Department of Chemistry and Biochemistry (DQB), Faculty of Sciences, University of Porto (FCUP), 4169-007 Porto, Portugal. Electronic address:
This work describes the successful design and synthesis of a new fluorescence resonance energy transfer (FRET)-based sensor, denoted as RD1. This sensor incorporates a robust dual-fluorophore design, which combines a rhodamine and a dansyl derivative, functionalized with a thiosemicarbazide group that acts as Hg(II) specific recognition site. A synthetic pathway was developed that allowed the efficient synthesis of RD1 with a remarkable overall yield of 44% over four steps, through microwave-assisted protocols.
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