Homogeneous nucleation and droplet growth in supersaturated argon vapor: the cryogenic nucleation pulse chamber.

J Chem Phys

Institut für Physikalische Chemie, Universität zu Köln, Luxemburger Strasse 116, D-50939 Köln, Germany.

Published: April 2006

We built a cryogenic nucleation pulse chamber for measuring homogeneous nucleation rates of argon. First measurements show that the growth rate of argon droplets at nucleation conditions is rather high so that nucleation and growth could not yet be decoupled. Nevertheless, the experiments permit an estimate of the onset of nucleation corresponding to a nucleation rate of J=10(7(+/-2)) cm(-3) s(-1) at temperatures 52

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http://dx.doi.org/10.1063/1.2186327DOI Listing

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