Removal of nickel ions from industrial effluents has been studied using activated alumina prepared by the galvanic oxidation of aluminum metal at ambient temperature as the adsorbent. The effect of various factors, such as initial concentration of nickel, contact time, dose of adsorbent and pH of the solution has been investigated. Batch and column type of adsorption studies have been made. The results indicate that the adsorption process is favored at pH 9. The adsorption data were fitted with suitable adsorption isotherm. The optimum conditions for the best adsorption have been evaluated for the following factors: dosage, contact time, pH, initial concentration of nickel ions and temperature. The process of regeneration of the adsorbent has also been studied.
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J Colloid Interface Sci
January 2025
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001 China. Electronic address:
Nickel-rich cobalt-free layered oxide cathode with Ni contents no fewer than 90 % has received extensive attention in the field of lithium-ion batteries due to its excellent specific capacity and low cost, but serious capacity degeneration induced by structural deterioration and interfacial instability greatly hamper their further development. Herein, the Sb-modified LiNiMnO materials from the interface to interior have been designed and fabricated to overcome the above issues. On the one hand, the introduction of Sb-ion in interior of grains can generate Sb-O chemical bond with high dissociation energy, which contributes to reinforce the chemical and structural stability.
View Article and Find Full Text PDFSci Adv
January 2025
State Key Laboratory of Organometallic Chemistry and Shanghai Hongkong Joint Laboratory in Chemical Synthesis, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (China).
Singly occupied molecular orbital (SOMO) activation of in situ generated enamines has achieved great success in (asymmetric) α-functionalization of carbonyl compounds. However, examples on the use of this activation mode in the transformations of other functional groups are rare, and the combination of SOMO activation with transition metal catalysis is still less explored. In the area of deoxygenative functionalization of amides, intermediates such as iminium ions and enamines were often generated in situ to result in the formation of α-functionalized amines.
View Article and Find Full Text PDFLuminescence
January 2025
Department of Electronics and Communication Engineering, Madan Mohan Malaviya University of Technology, Gorakhpur, Uttar Pradesh, India.
This study focuses on enhancing the performance of photodetector through the utilization of inorganic perovskite material. It emphasizes that the unique properties of perovskite materials contribute to the superior performance of the photodetector. The focus is on the design and enhancement of CsSnI-based photodetector having graphene oxide (GO) and PCBM as charge transport layer, analysing their potential for improved operation.
View Article and Find Full Text PDFEnviron Technol
January 2025
Department of Chemical Sciences, University of Johannesburg, Johannesburg, South Africa.
An increasing amount of water pollution is being caused by an increase in industrial activity. Recently, a wide range of methods, including extraction, chemical coagulation, membrane separation, chemical precipitation, adsorption, and ion exchange, have been used to remove heavy metals from aqueous solutions. The adsorption technique is believed to be the most highly effective method for eliminating heavy metals from wastewater among all of them.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Dipartimento di Scienze Fisiche e Chimiche, Universita degli Studi dellAquila, Coppito, 67100 L'Aquila, Italy.
We present a comprehensive theoretical study, using state-of-the-art density functional theory simulations, of the structural and electrochemical properties of amorphous pristine and iron-doped nickel-(oxy)hydroxide catalyst films for water oxidation in alkaline solutions, referred to as NiCat and Fe:NiCat. Our simulations accurately capture the structural changes in locally ordered units, as reported by X-ray absorption spectroscopy, when the catalyst films are activated by exposure to a positive potential. We emphasize the critical role of proton-coupled electron transfer in the reversible oxidation of Ni(II) to Ni(III/IV) during this activation.
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