The chemistry of 2,2,4,4-substituted pentane derivatives has been investigated with the aim of providing a flexible and versatile synthetic route to pyrimidinyl nitronyl nitroxides, in which the bis-N-oxy fragment is incorporated in a six-membered ring. The synthesis of 2,4-diamino-2,4-dimethylpentane and 2,4-bis(hydroxylamino)-2,4-dimethylpentane, convenient precursors of these nitroxides, is described and full characterization of a series of pyrimidinyl nitronyl nitroxides is reported, along with a preliminary study of their coordination properties.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/chem.200600061 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Pyrimidinyl nitronyl nitroxides.
Chemistry
June 2006
CEA-Grenoble, Département de Recherche Fondamentale sur la Matière Condensée, Service de Chimie Inorganique et Biologique,UMR-E3, CEA-UJF, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France.
The chemistry of 2,2,4,4-substituted pentane derivatives has been investigated with the aim of providing a flexible and versatile synthetic route to pyrimidinyl nitronyl nitroxides, in which the bis-N-oxy fragment is incorporated in a six-membered ring. The synthesis of 2,4-diamino-2,4-dimethylpentane and 2,4-bis(hydroxylamino)-2,4-dimethylpentane, convenient precursors of these nitroxides, is described and full characterization of a series of pyrimidinyl nitronyl nitroxides is reported, along with a preliminary study of their coordination properties.
View Article and Find Full Text PDFA versatile synthesis of new pyrimidinyl nitronyl nitroxides.
Chem Commun (Camb)
November 2003
Département de Recherche Fondamentale sur la Matiére Condensée, Service de Chimie Inorganique et Biologique, (UMR CNRS 5046), 17 Rue des Martyrs F38054, Grenoble Cedex 09, France.
Pyrimidinyl nitronyl nitroxides where the bis-N-oxy fragment is included in a six-membered ring were prepared from diacetonamine by a sequence of reactions including a Grignard reaction, a Ritter reaction and oxidation of the intermediate pyrimidine; the properties of the 2-phenyl-substituted representative are fully described.
View Article and Find Full Text PDFPreparation and magnetic properties of Mn(hfac)(2)-complexes of 2-(5-pyrimidinyl)- and 2-(3-pyridyl)-substituted nitronyl nitroxides.
Inorg Chem
May 2003
Departments of Chemistry and Materials Science, Graduate School of Science, Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
Mn(hfac)(2) complexes of [2-(5-pyrimidinyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H- imidazoline-1-oxyl 3-oxide] (1) and its 2-(3-pyridyl) analogue (2) were prepared. Both complexes formed similar dimer structures. However, their packing patterns were considerably different.
View Article and Find Full Text PDFRadical-copper wheels: structure and magnetism of hexanuclear hybrid arrays.
Inorg Chem
July 2001
Department of Applied Physics and Chemistry, The University of Electro-Communications, Chofu, Tokyo 182-8585, Japan.
Complexation of copper(II) bromide and chloride with 4-pyrimidinyl nitronyl nitroxide (4PMNN) as a bridging ligand gave discrete hexanuclear complexes carrying 12 spins, [CuX(2).(4PMNN)](6) [X = Br (1), Cl (2)], which crystallize in a trigonal space group. The crystallographic parameters are C(11)H(15)Br(2)CuN(4)O(2).
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!