Synchrotron-based sulfur X-ray absorption spectroscopy reveals considerable accumulation of organosulfur (e.g. thiols), pyrite and iron(II) sulfides in marine-archaeological wood preserved in seawater, e.g. for historical shipwrecks such as the Vasa and Mary Rose. In the museum, oxidation of the sulfur compounds in the presence of iron ions may cause severe acidity in the moist wood. This tutorial review discusses developments of conservation methods to remove acid and iron, and how to analyse and stabilise sulfur compounds in the wood.
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http://dx.doi.org/10.1039/b507010b | DOI Listing |
Chemistry
January 2025
Université de Montréal, FRQNT Centre in Green Chemistry and Catalysis, Centre for Continuous Flow Synthesis, Department of Chemistry, 1375 av. Thérèse Lavoie-Roux, Montréal, QC, H2V 0B3, Canada.
The pentafluorosulfanyl (SF-) group has been the subject of a surge of interest in the past decade, but there is still little practicality associated with its synthesis and installation. Herein is reported the first continuous flow synthesis of pentafluorosulfanyl chloride (SFCl), the most common reagent for the synthesis of SF-substituted compounds. The synthesis is based on inexpensive and easy-to-handle reagents: sulfur powder (S), trichloroisocyanuric acid (TCCA) and potassium fluoride (KF).
View Article and Find Full Text PDFClin Oral Investig
January 2025
Department of Pedodontics, Faculty of Dentistry, Erciyes University, 38039, Kayseri, Türkiye.
Objectives: This study evaluates the effect of different irrigation solutions for postoperative pain in the regenerative endodontic treatments (RET) of necrotic teeth with open apex.
Materials And Methods: This study included necrotic, deeply carious lower molars of 42 patients. Access cavities of the teeth were opened and working lengths were measured at the first visit.
Braz J Biol
January 2025
Universidade Federal de Santa Maria - UFSM, Departamento de Defesa Fitossanitária, Santa Maria, RS, Brasil.
Annual ryegrass (Lolium multiflorum Lam.) is one of the main weeds in subtropical cropping systems of Europe, Oceania and South America. Therefore, the hypothesis of this work is that the interaction between ammonium glufosinate and saflufenacil can be synergistic for ryegrass control.
View Article and Find Full Text PDFBraz J Biol
January 2025
Instituto Federal de Educação, Ciência e Tecnologia do Rio Grande do Sul - IFRS, Núcleo de Ciências Biológicas e Ambientais, Sertão, RS, Brasil.
The shrub Rubus erythroclados Mart. ex Hook.f.
View Article and Find Full Text PDFPLoS One
January 2025
Department of Biological Sciences, Purdue University Fort Wayne, Fort Wayne, Indiana, United States of America.
Present study aimed at improving the immune and antioxidant response of Pacific white shrimp (Litopenaeus vannamei) cultured at high stocking density fed with 0.2% supplementation of lauric acid (LA) and N-acetyl-L-cysteine (NAC). Shrimp (initial average weight = 0.
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